Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate

In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis­(benz­imid­azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure...

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Detalles Bibliográficos
Autores principales: Sun, Tao, Li, Ke, Lai, Yulin, Chen, Ruihuan, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008082/
https://www.ncbi.nlm.nih.gov/pubmed/21588483
http://dx.doi.org/10.1107/S1600536810030357
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author Sun, Tao
Li, Ke
Lai, Yulin
Chen, Ruihuan
Wu, Huilu
author_facet Sun, Tao
Li, Ke
Lai, Yulin
Chen, Ruihuan
Wu, Huilu
author_sort Sun, Tao
collection PubMed
description In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis­(benz­imid­azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of one of the nitro groups are disordered over two sets of sites with refined occupancies of 0.577 (11) and 0.423 (11).
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spelling pubmed-30080822010-12-30 Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate Sun, Tao Li, Ke Lai, Yulin Chen, Ruihuan Wu, Huilu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis­(benz­imid­azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of one of the nitro groups are disordered over two sets of sites with refined occupancies of 0.577 (11) and 0.423 (11). International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008082/ /pubmed/21588483 http://dx.doi.org/10.1107/S1600536810030357 Text en © Sun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Tao
Li, Ke
Lai, Yulin
Chen, Ruihuan
Wu, Huilu
Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title_full Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title_fullStr Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title_full_unstemmed Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title_short Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate
title_sort aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(ii) dipicrate ethanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008082/
https://www.ncbi.nlm.nih.gov/pubmed/21588483
http://dx.doi.org/10.1107/S1600536810030357
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