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Bis(μ-pyridine-2,4-dicarboxylato)-κ(3) N,O (2):O (2);κ(3) O (2):N,O (2)-bis[triaquamagnesium(II)]
In the title centrosymmetric Mg(II) complex, [Mg(2)(C(7)H(3)NO(4))(2)(H(2)O)(6)], each Mg cation is N,O-chelated by a pyridine-2,4-dicarboxylate dianion and is coordinated by three water molecules. A carboxylate O atom from the neighboring pyridine-2,4-dicarboxylate dianion bridges the Mg cation...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008092/ https://www.ncbi.nlm.nih.gov/pubmed/21588489 http://dx.doi.org/10.1107/S1600536810030722 |
| _version_ | 1782194500631789568 |
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| author | Zhang, Qing-Fu Han, Dan-Dan Pang, Jian-Dong Meng, Ning-Ning |
| author_facet | Zhang, Qing-Fu Han, Dan-Dan Pang, Jian-Dong Meng, Ning-Ning |
| author_sort | Zhang, Qing-Fu |
| collection | PubMed |
| description | In the title centrosymmetric Mg(II) complex, [Mg(2)(C(7)H(3)NO(4))(2)(H(2)O)(6)], each Mg cation is N,O-chelated by a pyridine-2,4-dicarboxylate dianion and is coordinated by three water molecules. A carboxylate O atom from the neighboring pyridine-2,4-dicarboxylate dianion bridges the Mg cation to complete the MgNO(5) distorted octahedral coordination geometry. The dinuclear complex molecules are linked by intermolecular O—H⋯O hydrogen bonding, forming a three-dimensional supramolecular structure. |
| format | Text |
| id | pubmed-3008092 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30080922010-12-30 Bis(μ-pyridine-2,4-dicarboxylato)-κ(3) N,O (2):O (2);κ(3) O (2):N,O (2)-bis[triaquamagnesium(II)] Zhang, Qing-Fu Han, Dan-Dan Pang, Jian-Dong Meng, Ning-Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric Mg(II) complex, [Mg(2)(C(7)H(3)NO(4))(2)(H(2)O)(6)], each Mg cation is N,O-chelated by a pyridine-2,4-dicarboxylate dianion and is coordinated by three water molecules. A carboxylate O atom from the neighboring pyridine-2,4-dicarboxylate dianion bridges the Mg cation to complete the MgNO(5) distorted octahedral coordination geometry. The dinuclear complex molecules are linked by intermolecular O—H⋯O hydrogen bonding, forming a three-dimensional supramolecular structure. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008092/ /pubmed/21588489 http://dx.doi.org/10.1107/S1600536810030722 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Qing-Fu Han, Dan-Dan Pang, Jian-Dong Meng, Ning-Ning Bis(μ-pyridine-2,4-dicarboxylato)-κ(3) N,O (2):O (2);κ(3) O (2):N,O (2)-bis[triaquamagnesium(II)] |
| title | Bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
N,O
(2):O
(2);κ(3)
O
(2):N,O
(2)-bis[triaquamagnesium(II)] |
| title_full | Bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
N,O
(2):O
(2);κ(3)
O
(2):N,O
(2)-bis[triaquamagnesium(II)] |
| title_fullStr | Bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
N,O
(2):O
(2);κ(3)
O
(2):N,O
(2)-bis[triaquamagnesium(II)] |
| title_full_unstemmed | Bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
N,O
(2):O
(2);κ(3)
O
(2):N,O
(2)-bis[triaquamagnesium(II)] |
| title_short | Bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
N,O
(2):O
(2);κ(3)
O
(2):N,O
(2)-bis[triaquamagnesium(II)] |
| title_sort | bis(μ-pyridine-2,4-dicarboxylato)-κ(3)
n,o
(2):o
(2);κ(3)
o
(2):n,o
(2)-bis[triaquamagnesium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008092/ https://www.ncbi.nlm.nih.gov/pubmed/21588489 http://dx.doi.org/10.1107/S1600536810030722 |
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