Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)

The asymmetric unit of the title compound, [Mo(C(14)H(12)NO)(2)O(2)], comprises half of the complex with the full mol­ecule generated by the application of twofold symmetry. The Mo(VI) atom is surrounded by two oxide O atoms and the two sets of N,O-donor atoms of the bidentate Schiff base ligands. T...

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Autores principales: Hatefi, Mehdi, Sheikhshoaie, Iran, Mirkhani, Valiollah, Moghadam, Majid, Kia, Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008093/
https://www.ncbi.nlm.nih.gov/pubmed/21588536
http://dx.doi.org/10.1107/S1600536810032836
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author Hatefi, Mehdi
Sheikhshoaie, Iran
Mirkhani, Valiollah
Moghadam, Majid
Kia, Reza
author_facet Hatefi, Mehdi
Sheikhshoaie, Iran
Mirkhani, Valiollah
Moghadam, Majid
Kia, Reza
author_sort Hatefi, Mehdi
collection PubMed
description The asymmetric unit of the title compound, [Mo(C(14)H(12)NO)(2)O(2)], comprises half of the complex with the full mol­ecule generated by the application of twofold symmetry. The Mo(VI) atom is surrounded by two oxide O atoms and the two sets of N,O-donor atoms of the bidentate Schiff base ligands. The resulting N(2)O(4) donor set defines a distorted octa­hedral coordination geometry. Inter­molecular C—H⋯O contacts link mol­ecules into chains along the b axis. The crystal structure is further stabilized by inter­molecular π–π inter­actions [ring centroid–centroid distance = 3.724 (6) Å].
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spelling pubmed-30080932010-12-30 Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI) Hatefi, Mehdi Sheikhshoaie, Iran Mirkhani, Valiollah Moghadam, Majid Kia, Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mo(C(14)H(12)NO)(2)O(2)], comprises half of the complex with the full mol­ecule generated by the application of twofold symmetry. The Mo(VI) atom is surrounded by two oxide O atoms and the two sets of N,O-donor atoms of the bidentate Schiff base ligands. The resulting N(2)O(4) donor set defines a distorted octa­hedral coordination geometry. Inter­molecular C—H⋯O contacts link mol­ecules into chains along the b axis. The crystal structure is further stabilized by inter­molecular π–π inter­actions [ring centroid–centroid distance = 3.724 (6) Å]. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008093/ /pubmed/21588536 http://dx.doi.org/10.1107/S1600536810032836 Text en © Hatefi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hatefi, Mehdi
Sheikhshoaie, Iran
Mirkhani, Valiollah
Moghadam, Majid
Kia, Reza
Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title_full Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title_fullStr Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title_full_unstemmed Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title_short Dioxidobis{2-[(E)-p-tolyl­imino­meth­yl]phenolato}molybdenum(VI)
title_sort dioxidobis{2-[(e)-p-tolyl­imino­meth­yl]phenolato}molybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008093/
https://www.ncbi.nlm.nih.gov/pubmed/21588536
http://dx.doi.org/10.1107/S1600536810032836
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