Acetato­chlorido[2,2′-(ethane-1,2-di­yl)di-1H-benzimidazole]­copper(II) monohydrate

In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]·H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2′-(ethane-1,2-di­yl)di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the...

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Detalles Bibliográficos
Autores principales: Li, Yu-xian, Yang, Huai-xia, Ding, Ya-nan, Meng, Xiang-ru
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008101/
https://www.ncbi.nlm.nih.gov/pubmed/21588549
http://dx.doi.org/10.1107/S160053681003326X
Descripción
Sumario:In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]·H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2′-(ethane-1,2-di­yl)di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the crystal, adjacent mol­ecules are linked through O—H⋯Cl, N—H⋯Cl, N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network.

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