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2-Amino-5-methyl­pyridinium 2-carb­oxy­benzoate

In the title salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), the hydrogen phthalate anion is essentially planar, with a maximum deviation of 0.011 (2) Å. In the crystal structure, the protonated N atom of the pyridine ring and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008103/
https://www.ncbi.nlm.nih.gov/pubmed/21588569
http://dx.doi.org/10.1107/S160053681003000X
Descripción
Sumario:In the title salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), the hydrogen phthalate anion is essentially planar, with a maximum deviation of 0.011 (2) Å. In the crystal structure, the protonated N atom of the pyridine ring and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the hydrogen phthalate anion, there is a very strong, almost symmetric, intra­molecular O—H⋯O hydrogen bond, generating an S(7) motif [O⋯O = 2.382 (3) Å]. Furthermore, these two molecular motif rings are connected by a bifurcated N—H⋯(O,O) hydrogen-bonded motif R (1) (2)(4), forming a supra­molecular ribbon along the b axis. The crystal structure is further stabilized by π–π inter­actions between the cations and anions [centroid–centroid distance = 3.6999 (10) Å].