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2-Amino-5-methylpyridinium 2-carboxybenzoate
In the title salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), the hydrogen phthalate anion is essentially planar, with a maximum deviation of 0.011 (2) Å. In the crystal structure, the protonated N atom of the pyridine ring and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008103/ https://www.ncbi.nlm.nih.gov/pubmed/21588569 http://dx.doi.org/10.1107/S160053681003000X |
Sumario: | In the title salt, C(6)H(9)N(2) (+)·C(8)H(5)O(4) (−), the hydrogen phthalate anion is essentially planar, with a maximum deviation of 0.011 (2) Å. In the crystal structure, the protonated N atom of the pyridine ring and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the hydrogen phthalate anion, there is a very strong, almost symmetric, intramolecular O—H⋯O hydrogen bond, generating an S(7) motif [O⋯O = 2.382 (3) Å]. Furthermore, these two molecular motif rings are connected by a bifurcated N—H⋯(O,O) hydrogen-bonded motif R (1) (2)(4), forming a supramolecular ribbon along the b axis. The crystal structure is further stabilized by π–π interactions between the cations and anions [centroid–centroid distance = 3.6999 (10) Å]. |
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