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1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide
The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008106/ https://www.ncbi.nlm.nih.gov/pubmed/21588768 http://dx.doi.org/10.1107/S1600536810034148 |
Sumario: | The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and C—H⋯S interactions. π–π interactions are present with distances of 3.2735 (17), 3.563 (2) and 3.664 (4)/3.688 (3) Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoromethoxy-substituted phenyl ring, and between the centroids of the trifluoromethoxy-substituted phenyl rings, respectively. The trifluoromethoxyphenyl group is disordered over two sites with an occupancy ratio of 0.642 (10):0.358 (10). |
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