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1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide
The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008106/ https://www.ncbi.nlm.nih.gov/pubmed/21588768 http://dx.doi.org/10.1107/S1600536810034148 |
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author | Ramzan, Muhammad Pervez, Humayun Tahir, M. Nawaz Yaqub, Muhammad Iqbal, Mohammad S. |
author_facet | Ramzan, Muhammad Pervez, Humayun Tahir, M. Nawaz Yaqub, Muhammad Iqbal, Mohammad S. |
author_sort | Ramzan, Muhammad |
collection | PubMed |
description | The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and C—H⋯S interactions. π–π interactions are present with distances of 3.2735 (17), 3.563 (2) and 3.664 (4)/3.688 (3) Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoromethoxy-substituted phenyl ring, and between the centroids of the trifluoromethoxy-substituted phenyl rings, respectively. The trifluoromethoxyphenyl group is disordered over two sites with an occupancy ratio of 0.642 (10):0.358 (10). |
format | Text |
id | pubmed-3008106 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081062010-12-30 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide Ramzan, Muhammad Pervez, Humayun Tahir, M. Nawaz Yaqub, Muhammad Iqbal, Mohammad S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O interactions. In the molecular structure, two S(5) ring motifs are formed by intramolecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and C—H⋯S interactions. π–π interactions are present with distances of 3.2735 (17), 3.563 (2) and 3.664 (4)/3.688 (3) Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoromethoxy-substituted phenyl ring, and between the centroids of the trifluoromethoxy-substituted phenyl rings, respectively. The trifluoromethoxyphenyl group is disordered over two sites with an occupancy ratio of 0.642 (10):0.358 (10). International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008106/ /pubmed/21588768 http://dx.doi.org/10.1107/S1600536810034148 Text en © Ramzan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ramzan, Muhammad Pervez, Humayun Tahir, M. Nawaz Yaqub, Muhammad Iqbal, Mohammad S. 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title_full | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title_fullStr | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title_full_unstemmed | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title_short | 1-(2-Oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
title_sort | 1-(2-oxoindolin-3-ylidene)-4-[2-(trifluoromethoxy)phenyl]thiosemicarbazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008106/ https://www.ncbi.nlm.nih.gov/pubmed/21588768 http://dx.doi.org/10.1107/S1600536810034148 |
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