Cargando…

1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide

The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O inter­actions. In the mol­ecular structure, two S(5) ring motifs are formed by intra­molecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramzan, Muhammad, Pervez, Humayun, Tahir, M. Nawaz, Yaqub, Muhammad, Iqbal, Mohammad S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008106/
https://www.ncbi.nlm.nih.gov/pubmed/21588768
http://dx.doi.org/10.1107/S1600536810034148
_version_ 1782194504117256192
author Ramzan, Muhammad
Pervez, Humayun
Tahir, M. Nawaz
Yaqub, Muhammad
Iqbal, Mohammad S.
author_facet Ramzan, Muhammad
Pervez, Humayun
Tahir, M. Nawaz
Yaqub, Muhammad
Iqbal, Mohammad S.
author_sort Ramzan, Muhammad
collection PubMed
description The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O inter­actions. In the mol­ecular structure, two S(5) ring motifs are formed by intra­molecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and C—H⋯S inter­actions. π–π inter­actions are present with distances of 3.2735 (17), 3.563 (2) and 3.664 (4)/3.688 (3) Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoro­meth­oxy-substituted phenyl ring, and between the centroids of the trifluoro­meth­oxy-substituted phenyl rings, respectively. The trifluoro­meth­oxy­phenyl group is disordered over two sites with an occupancy ratio of 0.642 (10):0.358 (10).
format Text
id pubmed-3008106
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30081062010-12-30 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide Ramzan, Muhammad Pervez, Humayun Tahir, M. Nawaz Yaqub, Muhammad Iqbal, Mohammad S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(16)H(11)F(3)N(4)O(2)S, is stabilized in the form of polymeric chains by N—H⋯O inter­actions. In the mol­ecular structure, two S(5) ring motifs are formed by intra­molecular N—H⋯N and N—H⋯O hydrogen bonding and two S(6) rings are present due to N—H⋯O and C—H⋯S inter­actions. π–π inter­actions are present with distances of 3.2735 (17), 3.563 (2) and 3.664 (4)/3.688 (3) Å between the centroids of the heterocyclic rings, between the centroids of the heterocyclic ring and trifluoro­meth­oxy-substituted phenyl ring, and between the centroids of the trifluoro­meth­oxy-substituted phenyl rings, respectively. The trifluoro­meth­oxy­phenyl group is disordered over two sites with an occupancy ratio of 0.642 (10):0.358 (10). International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008106/ /pubmed/21588768 http://dx.doi.org/10.1107/S1600536810034148 Text en © Ramzan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramzan, Muhammad
Pervez, Humayun
Tahir, M. Nawaz
Yaqub, Muhammad
Iqbal, Mohammad S.
1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title_full 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title_fullStr 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title_full_unstemmed 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title_short 1-(2-Oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
title_sort 1-(2-oxoindolin-3-yl­idene)-4-[2-(trifluoro­meth­oxy)phen­yl]thio­semi­carbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008106/
https://www.ncbi.nlm.nih.gov/pubmed/21588768
http://dx.doi.org/10.1107/S1600536810034148
work_keys_str_mv AT ramzanmuhammad 12oxoindolin3ylidene42trifluoromethoxyphenylthiosemicarbazide
AT pervezhumayun 12oxoindolin3ylidene42trifluoromethoxyphenylthiosemicarbazide
AT tahirmnawaz 12oxoindolin3ylidene42trifluoromethoxyphenylthiosemicarbazide
AT yaqubmuhammad 12oxoindolin3ylidene42trifluoromethoxyphenylthiosemicarbazide
AT iqbalmohammads 12oxoindolin3ylidene42trifluoromethoxyphenylthiosemicarbazide