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2-Amino-5-methylpyridinium 2-hydroxybenzoate
In the title compound, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the protonated 2-amino-5-methylpyridinium cation and the 2-hydroxybenzoate anion are both essentially planar, with maximum deviations of 0.026 (2) and 0.034 (1) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008107/ https://www.ncbi.nlm.nih.gov/pubmed/21588618 http://dx.doi.org/10.1107/S1600536810030928 |
Sumario: | In the title compound, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the protonated 2-amino-5-methylpyridinium cation and the 2-hydroxybenzoate anion are both essentially planar, with maximum deviations of 0.026 (2) and 0.034 (1) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. In the solid state, the anions are linked to the cations via pairs of intermolecular N—H⋯O hydrogen bonds forming R (2) (2)(8) ring motifs. The crystal structure is further stabilized by N—H⋯O and C—H⋯O interactions which link the molecules into chains along [010]. A π–π stacking interaction [centroid–centroid-distance = 3.740 (2) Å] is also observed. |
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