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2-Amino-5-methylpyridinium 2-hydroxybenzoate
In the title compound, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the protonated 2-amino-5-methylpyridinium cation and the 2-hydroxybenzoate anion are both essentially planar, with maximum deviations of 0.026 (2) and 0.034 (1) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008107/ https://www.ncbi.nlm.nih.gov/pubmed/21588618 http://dx.doi.org/10.1107/S1600536810030928 |
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author | Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Quah, Ching Kheng |
collection | PubMed |
description | In the title compound, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the protonated 2-amino-5-methylpyridinium cation and the 2-hydroxybenzoate anion are both essentially planar, with maximum deviations of 0.026 (2) and 0.034 (1) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. In the solid state, the anions are linked to the cations via pairs of intermolecular N—H⋯O hydrogen bonds forming R (2) (2)(8) ring motifs. The crystal structure is further stabilized by N—H⋯O and C—H⋯O interactions which link the molecules into chains along [010]. A π–π stacking interaction [centroid–centroid-distance = 3.740 (2) Å] is also observed. |
format | Text |
id | pubmed-3008107 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081072010-12-30 2-Amino-5-methylpyridinium 2-hydroxybenzoate Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(9)N(2) (+)·C(7)H(5)O(3) (−), the protonated 2-amino-5-methylpyridinium cation and the 2-hydroxybenzoate anion are both essentially planar, with maximum deviations of 0.026 (2) and 0.034 (1) Å, respectively. The anion is stabilized by an intramolecular O—H⋯O hydrogen bond, which forms an S(6) ring motif. In the solid state, the anions are linked to the cations via pairs of intermolecular N—H⋯O hydrogen bonds forming R (2) (2)(8) ring motifs. The crystal structure is further stabilized by N—H⋯O and C—H⋯O interactions which link the molecules into chains along [010]. A π–π stacking interaction [centroid–centroid-distance = 3.740 (2) Å] is also observed. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008107/ /pubmed/21588618 http://dx.doi.org/10.1107/S1600536810030928 Text en © Quah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title | 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title_full | 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title_fullStr | 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title_full_unstemmed | 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title_short | 2-Amino-5-methylpyridinium 2-hydroxybenzoate |
title_sort | 2-amino-5-methylpyridinium 2-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008107/ https://www.ncbi.nlm.nih.gov/pubmed/21588618 http://dx.doi.org/10.1107/S1600536810030928 |
work_keys_str_mv | AT quahchingkheng 2amino5methylpyridinium2hydroxybenzoate AT hemamalinimadhukar 2amino5methylpyridinium2hydroxybenzoate AT funhoongkun 2amino5methylpyridinium2hydroxybenzoate |