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2,3;5,6-Di-O-isopropylidene-1-O-(2-phenylacetyl)-α-d-mannofuranose
The title compound, C(20)H(26)O(7), was prepared by esterification of 2,3;5,6-di-O-isopropylidene-α-d-mannofuranose with phenylacetic acid under standard DCC/DMAP (DCC = dicyclohexylcarbodiimide and DMAP = 4-dimethylaminopyridine) conditions. The solid-state structure confirms the retention of t...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008108/ https://www.ncbi.nlm.nih.gov/pubmed/21588686 http://dx.doi.org/10.1107/S1600536810032368 |
Sumario: | The title compound, C(20)H(26)O(7), was prepared by esterification of 2,3;5,6-di-O-isopropylidene-α-d-mannofuranose with phenylacetic acid under standard DCC/DMAP (DCC = dicyclohexylcarbodiimide and DMAP = 4-dimethylaminopyridine) conditions. The solid-state structure confirms the retention of the α-configuration at the anomeric C atom. The compound is characterized by a relatively rigid framework with only a few degrees of freedom. Comparison with other di-O-isopropylidenemannofuranose derivatives shows the main differences to be associated with the flexible dimethyldioxolane ring, and that there are only small differences for the 2,3-O-isopropylidene-α-d-mannofuranose backbone. The packing is marked by a large number of weak C—H⋯O interactions. |
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