Cargando…
Aqua(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitrobenzoato-κO (1))copper(II) tetrahydrofuran monosolvate
The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a pentacoordinate Cu(II) atom bound by two monodentate carboxylate ligands, a bidentate 2,2′-bipyridine molecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water molecule. The resulting N(2)O(3)...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008109/ https://www.ncbi.nlm.nih.gov/pubmed/21588481 http://dx.doi.org/10.1107/S1600536810030436 |
Sumario: | The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a pentacoordinate Cu(II) atom bound by two monodentate carboxylate ligands, a bidentate 2,2′-bipyridine molecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water molecule. The resulting N(2)O(3) donor set defines a distorted square-pyramidal geometry with the coordinated water molecule in the apical position. In the crystal, the presence of O—H(w)⋯O(c) (w = water and c = carbonyl) hydrogen bonding leads to the formation of a supramolecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent molecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex molecules and are held in place via C—H⋯O interactions. |
---|