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Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate

The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a penta­coordinate Cu(II) atom bound by two monodentate carboxyl­ate ligands, a bidentate 2,2′-bipyridine mol­ecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water mol­ecule. The resulting N(2)O(3)...

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Detalles Bibliográficos
Autores principales: Abdullah, Norbani, Mohamadin, M. I., Safwan, A. P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008109/
https://www.ncbi.nlm.nih.gov/pubmed/21588481
http://dx.doi.org/10.1107/S1600536810030436
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author Abdullah, Norbani
Mohamadin, M. I.
Safwan, A. P.
Tiekink, Edward R. T.
author_facet Abdullah, Norbani
Mohamadin, M. I.
Safwan, A. P.
Tiekink, Edward R. T.
author_sort Abdullah, Norbani
collection PubMed
description The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a penta­coordinate Cu(II) atom bound by two monodentate carboxyl­ate ligands, a bidentate 2,2′-bipyridine mol­ecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water mol­ecule. The resulting N(2)O(3) donor set defines a distorted square-pyramidal geometry with the coordinated water mol­ecule in the apical position. In the crystal, the presence of O—H(w)⋯O(c) (w = water and c = carbon­yl) hydrogen bonding leads to the formation of a supra­molecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent mol­ecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex mol­ecules and are held in place via C—H⋯O inter­actions.
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spelling pubmed-30081092010-12-30 Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate Abdullah, Norbani Mohamadin, M. I. Safwan, A. P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a penta­coordinate Cu(II) atom bound by two monodentate carboxyl­ate ligands, a bidentate 2,2′-bipyridine mol­ecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water mol­ecule. The resulting N(2)O(3) donor set defines a distorted square-pyramidal geometry with the coordinated water mol­ecule in the apical position. In the crystal, the presence of O—H(w)⋯O(c) (w = water and c = carbon­yl) hydrogen bonding leads to the formation of a supra­molecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent mol­ecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex mol­ecules and are held in place via C—H⋯O inter­actions. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008109/ /pubmed/21588481 http://dx.doi.org/10.1107/S1600536810030436 Text en © Abdullah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abdullah, Norbani
Mohamadin, M. I.
Safwan, A. P.
Tiekink, Edward R. T.
Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title_full Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title_fullStr Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title_full_unstemmed Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title_short Aqua­(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitro­benzoato-κO (1))copper(II) tetra­hydro­furan monosolvate
title_sort aqua­(2,2′-bipyridine-κ(2) n,n′)(3,5-dinitro­benzoato-κo (1))copper(ii) tetra­hydro­furan monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008109/
https://www.ncbi.nlm.nih.gov/pubmed/21588481
http://dx.doi.org/10.1107/S1600536810030436
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