Cargando…
Aqua(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitrobenzoato-κO (1))copper(II) tetrahydrofuran monosolvate
The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a pentacoordinate Cu(II) atom bound by two monodentate carboxylate ligands, a bidentate 2,2′-bipyridine molecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water molecule. The resulting N(2)O(3)...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008109/ https://www.ncbi.nlm.nih.gov/pubmed/21588481 http://dx.doi.org/10.1107/S1600536810030436 |
_version_ | 1782194504841822208 |
---|---|
author | Abdullah, Norbani Mohamadin, M. I. Safwan, A. P. Tiekink, Edward R. T. |
author_facet | Abdullah, Norbani Mohamadin, M. I. Safwan, A. P. Tiekink, Edward R. T. |
author_sort | Abdullah, Norbani |
collection | PubMed |
description | The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a pentacoordinate Cu(II) atom bound by two monodentate carboxylate ligands, a bidentate 2,2′-bipyridine molecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water molecule. The resulting N(2)O(3) donor set defines a distorted square-pyramidal geometry with the coordinated water molecule in the apical position. In the crystal, the presence of O—H(w)⋯O(c) (w = water and c = carbonyl) hydrogen bonding leads to the formation of a supramolecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent molecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex molecules and are held in place via C—H⋯O interactions. |
format | Text |
id | pubmed-3008109 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081092010-12-30 Aqua(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitrobenzoato-κO (1))copper(II) tetrahydrofuran monosolvate Abdullah, Norbani Mohamadin, M. I. Safwan, A. P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(7)H(3)N(2)O(6))(2)(C(10)H(8)N(2))(H(2)O)]·C(4)H(8)O, features a pentacoordinate Cu(II) atom bound by two monodentate carboxylate ligands, a bidentate 2,2′-bipyridine molecule [dihedral angle between pyridine rings = 5.0 (2)°] and a water molecule. The resulting N(2)O(3) donor set defines a distorted square-pyramidal geometry with the coordinated water molecule in the apical position. In the crystal, the presence of O—H(w)⋯O(c) (w = water and c = carbonyl) hydrogen bonding leads to the formation of a supramolecular chain propagating along the c axis, which associates into a double chain via C—H⋯ O and π–π contacts between pyridyl rings [centroid–centroid distance = 3.527 (3) Å]. The solvent molecules, which are disordered over two orientations in a 0.678 (11):0.322 (11) ratio, occupy voids defined by the complex molecules and are held in place via C—H⋯O interactions. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008109/ /pubmed/21588481 http://dx.doi.org/10.1107/S1600536810030436 Text en © Abdullah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Abdullah, Norbani Mohamadin, M. I. Safwan, A. P. Tiekink, Edward R. T. Aqua(2,2′-bipyridine-κ(2) N,N′)(3,5-dinitrobenzoato-κO (1))copper(II) tetrahydrofuran monosolvate |
title | Aqua(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitrobenzoato-κO
(1))copper(II) tetrahydrofuran monosolvate |
title_full | Aqua(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitrobenzoato-κO
(1))copper(II) tetrahydrofuran monosolvate |
title_fullStr | Aqua(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitrobenzoato-κO
(1))copper(II) tetrahydrofuran monosolvate |
title_full_unstemmed | Aqua(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitrobenzoato-κO
(1))copper(II) tetrahydrofuran monosolvate |
title_short | Aqua(2,2′-bipyridine-κ(2)
N,N′)(3,5-dinitrobenzoato-κO
(1))copper(II) tetrahydrofuran monosolvate |
title_sort | aqua(2,2′-bipyridine-κ(2)
n,n′)(3,5-dinitrobenzoato-κo
(1))copper(ii) tetrahydrofuran monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008109/ https://www.ncbi.nlm.nih.gov/pubmed/21588481 http://dx.doi.org/10.1107/S1600536810030436 |
work_keys_str_mv | AT abdullahnorbani aqua22bipyridinek2nn35dinitrobenzoatoko1copperiitetrahydrofuranmonosolvate AT mohamadinmi aqua22bipyridinek2nn35dinitrobenzoatoko1copperiitetrahydrofuranmonosolvate AT safwanap aqua22bipyridinek2nn35dinitrobenzoatoko1copperiitetrahydrofuranmonosolvate AT tiekinkedwardrt aqua22bipyridinek2nn35dinitrobenzoatoko1copperiitetrahydrofuranmonosolvate |