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Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2) N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008117/ https://www.ncbi.nlm.nih.gov/pubmed/21588558 http://dx.doi.org/10.1107/S1600536810033611 |
Sumario: | The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ(2),κ(2)-bridging mode involving pyridine N atoms for one ligand, and a μ(2),κ(4)-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag(+) cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H⋯O, C—H⋯O, and C—F⋯O interactions. |
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