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Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]

The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-mol­ecules of N,N′-bis­(2-pyridyl­meth­yl)oxalamide (each of which is dis­posed about a centre of inversion) and a trifluoro­methane­sulfonate anion. Distinct coordination modes are...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Miller, Tyler, Poplaukhin, Pavel, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008117/
https://www.ncbi.nlm.nih.gov/pubmed/21588558
http://dx.doi.org/10.1107/S1600536810033611
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author Arman, Hadi D.
Miller, Tyler
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Miller, Tyler
Poplaukhin, Pavel
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-mol­ecules of N,N′-bis­(2-pyridyl­meth­yl)oxalamide (each of which is dis­posed about a centre of inversion) and a trifluoro­methane­sulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ(2),κ(2)-bridging mode involving pyridine N atoms for one ligand, and a μ(2),κ(4)-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag(+) cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoro­methane­sulfonate anions via N—H⋯O, C—H⋯O, and C—F⋯O inter­actions.
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spelling pubmed-30081172010-12-30 Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)] Arman, Hadi D. Miller, Tyler Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-mol­ecules of N,N′-bis­(2-pyridyl­meth­yl)oxalamide (each of which is dis­posed about a centre of inversion) and a trifluoro­methane­sulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ(2),κ(2)-bridging mode involving pyridine N atoms for one ligand, and a μ(2),κ(4)-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag(+) cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoro­methane­sulfonate anions via N—H⋯O, C—H⋯O, and C—F⋯O inter­actions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008117/ /pubmed/21588558 http://dx.doi.org/10.1107/S1600536810033611 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arman, Hadi D.
Miller, Tyler
Poplaukhin, Pavel
Tiekink, Edward R. T.
Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title_full Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title_fullStr Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title_full_unstemmed Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title_short Poly[[bis­[μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) N:N′]disilver(I)] bis­(trifluoro­methane­sulfonate)]
title_sort poly[[bis­[μ(2)-n,n′-bis­(2-pyridyl­meth­yl)oxalamide-κ(4) n,o:n′,o′][μ(2)-n,n′-bis­(2-pyridyl­meth­yl)oxalamide-κ(2) n:n′]disilver(i)] bis­(trifluoro­methane­sulfonate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008117/
https://www.ncbi.nlm.nih.gov/pubmed/21588558
http://dx.doi.org/10.1107/S1600536810033611
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