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Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2) N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008117/ https://www.ncbi.nlm.nih.gov/pubmed/21588558 http://dx.doi.org/10.1107/S1600536810033611 |
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author | Arman, Hadi D. Miller, Tyler Poplaukhin, Pavel Tiekink, Edward R. T. |
author_facet | Arman, Hadi D. Miller, Tyler Poplaukhin, Pavel Tiekink, Edward R. T. |
author_sort | Arman, Hadi D. |
collection | PubMed |
description | The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ(2),κ(2)-bridging mode involving pyridine N atoms for one ligand, and a μ(2),κ(4)-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag(+) cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H⋯O, C—H⋯O, and C—F⋯O interactions. |
format | Text |
id | pubmed-3008117 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081172010-12-30 Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2) N:N′]disilver(I)] bis(trifluoromethanesulfonate)] Arman, Hadi D. Miller, Tyler Poplaukhin, Pavel Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title salt, [Ag(C(14)H(14)N(4)O(2))(1.5)](CF(3)SO(3)), comprises a Ag(+) cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ(2),κ(2)-bridging mode involving pyridine N atoms for one ligand, and a μ(2),κ(4)-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag(+) cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H⋯O, C—H⋯O, and C—F⋯O interactions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008117/ /pubmed/21588558 http://dx.doi.org/10.1107/S1600536810033611 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Arman, Hadi D. Miller, Tyler Poplaukhin, Pavel Tiekink, Edward R. T. Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2) N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title | Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4)
N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2)
N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title_full | Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4)
N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2)
N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title_fullStr | Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4)
N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2)
N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title_full_unstemmed | Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4)
N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2)
N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title_short | Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4)
N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2)
N:N′]disilver(I)] bis(trifluoromethanesulfonate)] |
title_sort | poly[[bis[μ(2)-n,n′-bis(2-pyridylmethyl)oxalamide-κ(4)
n,o:n′,o′][μ(2)-n,n′-bis(2-pyridylmethyl)oxalamide-κ(2)
n:n′]disilver(i)] bis(trifluoromethanesulfonate)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008117/ https://www.ncbi.nlm.nih.gov/pubmed/21588558 http://dx.doi.org/10.1107/S1600536810033611 |
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