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Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV)
In the title compound, [Hf(C(15)H(11)O(2))(4)], the Hf(IV) atom is coordinated by four 1,3-diphenylpropane-1,3-dionato ligands with an average Hf—O distance of 2.17 (3) Å and O—Hf—O bite angles varying from 74.5 (1) to 75.02 (9)°. The coordination polyhedron shows a slightly distorted Archimedean s...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008122/ https://www.ncbi.nlm.nih.gov/pubmed/21588480 http://dx.doi.org/10.1107/S1600536810030400 |
| _version_ | 1782194507990695936 |
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| author | Viljoen, J. Augustinus Visser, Hendrik G. Roodt, Andreas |
| author_facet | Viljoen, J. Augustinus Visser, Hendrik G. Roodt, Andreas |
| author_sort | Viljoen, J. Augustinus |
| collection | PubMed |
| description | In the title compound, [Hf(C(15)H(11)O(2))(4)], the Hf(IV) atom is coordinated by four 1,3-diphenylpropane-1,3-dionato ligands with an average Hf—O distance of 2.17 (3) Å and O—Hf—O bite angles varying from 74.5 (1) to 75.02 (9)°. The coordination polyhedron shows a slightly distorted Archimedean square-antiprismatic geometry. The crystal packing is stabilized by weak C—H⋯O interactions. |
| format | Text |
| id | pubmed-3008122 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30081222010-12-30 Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) Viljoen, J. Augustinus Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hf(C(15)H(11)O(2))(4)], the Hf(IV) atom is coordinated by four 1,3-diphenylpropane-1,3-dionato ligands with an average Hf—O distance of 2.17 (3) Å and O—Hf—O bite angles varying from 74.5 (1) to 75.02 (9)°. The coordination polyhedron shows a slightly distorted Archimedean square-antiprismatic geometry. The crystal packing is stabilized by weak C—H⋯O interactions. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008122/ /pubmed/21588480 http://dx.doi.org/10.1107/S1600536810030400 Text en © Viljoen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Viljoen, J. Augustinus Visser, Hendrik G. Roodt, Andreas Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title | Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title_full | Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title_fullStr | Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title_full_unstemmed | Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title_short | Tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(IV) |
| title_sort | tetrakis(1,3-diphenylpropane-1,3-dionato)hafnium(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008122/ https://www.ncbi.nlm.nih.gov/pubmed/21588480 http://dx.doi.org/10.1107/S1600536810030400 |
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