[(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)

In the title complex, [Co(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Co(II) atom exhibits a pseudo-octa­hedral coordination geometry, comprising two N-donor atoms from a bidentate chelate (4-bromo­phen­yl)(2-pyridyl­methyl­idene)amine (ppa(Br)) ligand [Co—N = 2.098 (2) and 2.209 (2) Å] and four O-dono...

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Detalles Bibliográficos
Autores principales: Harding, Phimphaka, Harding, David J., Soponrat, Nitisastr, Adams, Harry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008124/
https://www.ncbi.nlm.nih.gov/pubmed/21588537
http://dx.doi.org/10.1107/S1600536810032757
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author Harding, Phimphaka
Harding, David J.
Soponrat, Nitisastr
Adams, Harry
author_facet Harding, Phimphaka
Harding, David J.
Soponrat, Nitisastr
Adams, Harry
author_sort Harding, Phimphaka
collection PubMed
description In the title complex, [Co(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Co(II) atom exhibits a pseudo-octa­hedral coordination geometry, comprising two N-donor atoms from a bidentate chelate (4-bromo­phen­yl)(2-pyridyl­methyl­idene)amine (ppa(Br)) ligand [Co—N = 2.098 (2) and 2.209 (2) Å] and four O-donor atoms from two bidentate chelate 1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionate (hfac) ligands [Co—O range = 2.0452 (19)–2.0796 (19) Å]. The packing of the structure involves weak π–π inter­actions between the pyridyl and benzene rings of neighbouring ppa(Br) ligands [centroid–centroid distance = 3.928 (2) Å] and inter­actions between the Br atom on the ppa(Br) ligand and the hfac ligand [Br⋯C = 3.531 (2) Å].
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spelling pubmed-30081242010-12-30 [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II) Harding, Phimphaka Harding, David J. Soponrat, Nitisastr Adams, Harry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Co(II) atom exhibits a pseudo-octa­hedral coordination geometry, comprising two N-donor atoms from a bidentate chelate (4-bromo­phen­yl)(2-pyridyl­methyl­idene)amine (ppa(Br)) ligand [Co—N = 2.098 (2) and 2.209 (2) Å] and four O-donor atoms from two bidentate chelate 1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionate (hfac) ligands [Co—O range = 2.0452 (19)–2.0796 (19) Å]. The packing of the structure involves weak π–π inter­actions between the pyridyl and benzene rings of neighbouring ppa(Br) ligands [centroid–centroid distance = 3.928 (2) Å] and inter­actions between the Br atom on the ppa(Br) ligand and the hfac ligand [Br⋯C = 3.531 (2) Å]. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008124/ /pubmed/21588537 http://dx.doi.org/10.1107/S1600536810032757 Text en © Harding et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harding, Phimphaka
Harding, David J.
Soponrat, Nitisastr
Adams, Harry
[(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_full [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_fullStr [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_full_unstemmed [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_short [(4-Bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) N,N′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) O,O′)cobalt(II)
title_sort [(4-bromo­phen­yl)(2-pyridyl­methyl­idene)amine-κ(2) n,n′]bis­(1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato-κ(2) o,o′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008124/
https://www.ncbi.nlm.nih.gov/pubmed/21588537
http://dx.doi.org/10.1107/S1600536810032757
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