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Diaquabis(perchlorato)(1,10-phenanthroline)copper(II)
In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008125/ https://www.ncbi.nlm.nih.gov/pubmed/21588543 http://dx.doi.org/10.1107/S160053681003312X |
Sumario: | In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octahedral environment. The crystal packing is stabilized by O—H⋯O hydrogen bonds between the water molecules and the perchlorate anions. In addition, the organic molecules are associated by π–π stacking interactions between symmetry-equivalent antiparallel non-nitrogen aromatic rings, with interplanar distances of 3.543 (2) Å. |
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