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Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)

In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water mol­ecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms...

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Detalles Bibliográficos
Autores principales: Kaabi, Kamel, El Glaoui, Meher, Zeller, Matthias, Ben Nasr, Cherif
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008125/
https://www.ncbi.nlm.nih.gov/pubmed/21588543
http://dx.doi.org/10.1107/S160053681003312X
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author Kaabi, Kamel
El Glaoui, Meher
Zeller, Matthias
Ben Nasr, Cherif
author_facet Kaabi, Kamel
El Glaoui, Meher
Zeller, Matthias
Ben Nasr, Cherif
author_sort Kaabi, Kamel
collection PubMed
description In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water mol­ecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octa­hedral environment. The crystal packing is stabilized by O—H⋯O hydrogen bonds between the water mol­ecules and the perchlorate anions. In addition, the organic mol­ecules are associated by π–π stacking inter­actions between symmetry-equivalent anti­parallel non-nitro­gen aromatic rings, with inter­planar distances of 3.543 (2) Å.
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spelling pubmed-30081252010-12-30 Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II) Kaabi, Kamel El Glaoui, Meher Zeller, Matthias Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water mol­ecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octa­hedral environment. The crystal packing is stabilized by O—H⋯O hydrogen bonds between the water mol­ecules and the perchlorate anions. In addition, the organic mol­ecules are associated by π–π stacking inter­actions between symmetry-equivalent anti­parallel non-nitro­gen aromatic rings, with inter­planar distances of 3.543 (2) Å. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008125/ /pubmed/21588543 http://dx.doi.org/10.1107/S160053681003312X Text en © Kaabi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kaabi, Kamel
El Glaoui, Meher
Zeller, Matthias
Ben Nasr, Cherif
Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title_full Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title_fullStr Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title_full_unstemmed Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title_short Diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(II)
title_sort diaqua­bis­(perchlorato)(1,10-phenanthroline)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008125/
https://www.ncbi.nlm.nih.gov/pubmed/21588543
http://dx.doi.org/10.1107/S160053681003312X
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