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Diaquabis(perchlorato)(1,10-phenanthroline)copper(II)
In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008125/ https://www.ncbi.nlm.nih.gov/pubmed/21588543 http://dx.doi.org/10.1107/S160053681003312X |
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author | Kaabi, Kamel El Glaoui, Meher Zeller, Matthias Ben Nasr, Cherif |
author_facet | Kaabi, Kamel El Glaoui, Meher Zeller, Matthias Ben Nasr, Cherif |
author_sort | Kaabi, Kamel |
collection | PubMed |
description | In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octahedral environment. The crystal packing is stabilized by O—H⋯O hydrogen bonds between the water molecules and the perchlorate anions. In addition, the organic molecules are associated by π–π stacking interactions between symmetry-equivalent antiparallel non-nitrogen aromatic rings, with interplanar distances of 3.543 (2) Å. |
format | Text |
id | pubmed-3008125 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081252010-12-30 Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) Kaabi, Kamel El Glaoui, Meher Zeller, Matthias Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water molecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octahedral environment. The crystal packing is stabilized by O—H⋯O hydrogen bonds between the water molecules and the perchlorate anions. In addition, the organic molecules are associated by π–π stacking interactions between symmetry-equivalent antiparallel non-nitrogen aromatic rings, with interplanar distances of 3.543 (2) Å. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008125/ /pubmed/21588543 http://dx.doi.org/10.1107/S160053681003312X Text en © Kaabi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kaabi, Kamel El Glaoui, Meher Zeller, Matthias Ben Nasr, Cherif Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title | Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title_full | Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title_fullStr | Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title_full_unstemmed | Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title_short | Diaquabis(perchlorato)(1,10-phenanthroline)copper(II) |
title_sort | diaquabis(perchlorato)(1,10-phenanthroline)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008125/ https://www.ncbi.nlm.nih.gov/pubmed/21588543 http://dx.doi.org/10.1107/S160053681003312X |
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