Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]

In the centrosymmetric binuclear title compound, [Pb(2)(N(3))(2)(NCS)(2)(C(12)H(8)N(2))(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thio­cyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this sq...

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Autores principales: Mohammadnezhad, Gholamhossein, Ghanbarpour, Ali Reza, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008129/
https://www.ncbi.nlm.nih.gov/pubmed/21588524
http://dx.doi.org/10.1107/S1600536810032125
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author Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
author_facet Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
author_sort Mohammadnezhad, Gholamhossein
collection PubMed
description In the centrosymmetric binuclear title compound, [Pb(2)(N(3))(2)(NCS)(2)(C(12)H(8)N(2))(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thio­cyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)°. The Pb(II) atom is in a Ψ-square-anti­prismaic coordination.
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spelling pubmed-30081292010-12-30 Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)] Mohammadnezhad, Gholamhossein Ghanbarpour, Ali Reza Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title compound, [Pb(2)(N(3))(2)(NCS)(2)(C(12)H(8)N(2))(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thio­cyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)°. The Pb(II) atom is in a Ψ-square-anti­prismaic coordination. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008129/ /pubmed/21588524 http://dx.doi.org/10.1107/S1600536810032125 Text en © Mohammadnezhad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mohammadnezhad, Gholamhossein
Ghanbarpour, Ali Reza
Amini, Mostafa M.
Ng, Seik Weng
Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title_full Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title_fullStr Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title_full_unstemmed Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title_short Di-μ-azido-κ(4) N (1):N (1)-bis­[(1,10-phen­anthroline-κ(2) N,N′)(thio­cyanato-κN)lead(II)]
title_sort di-μ-azido-κ(4) n (1):n (1)-bis­[(1,10-phen­anthroline-κ(2) n,n′)(thio­cyanato-κn)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008129/
https://www.ncbi.nlm.nih.gov/pubmed/21588524
http://dx.doi.org/10.1107/S1600536810032125
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