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Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2) N (1),O)tin(IV)
The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half molecules. The half-molecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both molecules feature seven-co...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008135/ https://www.ncbi.nlm.nih.gov/pubmed/21588539 http://dx.doi.org/10.1107/S1600536810032733 |
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author | Ng, Seik Weng |
author_facet | Ng, Seik Weng |
author_sort | Ng, Seik Weng |
collection | PubMed |
description | The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half molecules. The half-molecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both molecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) pentagonal-bipyramidal coordination environments. The carboxylate anions N,O-chelate to the Sn atom. In the crystal, the carboxylate O atoms not involved in coordination serve as acceptors for O—H⋯O hydrogen bonds from adjacent water molecules, generating a three-dimensional network. |
format | Text |
id | pubmed-3008135 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081352010-12-30 Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2) N (1),O)tin(IV) Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half molecules. The half-molecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both molecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) pentagonal-bipyramidal coordination environments. The carboxylate anions N,O-chelate to the Sn atom. In the crystal, the carboxylate O atoms not involved in coordination serve as acceptors for O—H⋯O hydrogen bonds from adjacent water molecules, generating a three-dimensional network. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008135/ /pubmed/21588539 http://dx.doi.org/10.1107/S1600536810032733 Text en © Seik Weng Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ng, Seik Weng Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2) N (1),O)tin(IV) |
title | Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
N
(1),O)tin(IV) |
title_full | Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
N
(1),O)tin(IV) |
title_fullStr | Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
N
(1),O)tin(IV) |
title_full_unstemmed | Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
N
(1),O)tin(IV) |
title_short | Monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
N
(1),O)tin(IV) |
title_sort | monoclinic modification of aquadi-n-butylbis(pyrazine-2-carboxylato-κ(2)
n
(1),o)tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008135/ https://www.ncbi.nlm.nih.gov/pubmed/21588539 http://dx.doi.org/10.1107/S1600536810032733 |
work_keys_str_mv | AT ngseikweng monoclinicmodificationofaquadinbutylbispyrazine2carboxylatok2n1otiniv |