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Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)

The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half mol­ecules. The half-mol­ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol­ecules feature seven-co...

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Autor principal: Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008135/
https://www.ncbi.nlm.nih.gov/pubmed/21588539
http://dx.doi.org/10.1107/S1600536810032733
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author Ng, Seik Weng
author_facet Ng, Seik Weng
author_sort Ng, Seik Weng
collection PubMed
description The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half mol­ecules. The half-mol­ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol­ecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) penta­gonal-bipyramidal coordination environments. The carboxyl­ate anions N,O-chelate to the Sn atom. In the crystal, the carboxyl­ate O atoms not involved in coordination serve as acceptors for O—H⋯O hydrogen bonds from adjacent water mol­ecules, generating a three-dimensional network.
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spelling pubmed-30081352010-12-30 Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV) Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title organotin(IV) compound, [Sn(C(4)H(9))(2)(C(5)H(3)N(2)O(2))(2)(H(2)O)], contains one-and-a-half mol­ecules. The half-mol­ecule is completed by crystallographic twofold symmetry, with its Sn and water O atoms lying on the rotation axis. Both mol­ecules feature seven-coordinate Sn atoms in trans-C(2)SnN(2)O(3) penta­gonal-bipyramidal coordination environments. The carboxyl­ate anions N,O-chelate to the Sn atom. In the crystal, the carboxyl­ate O atoms not involved in coordination serve as acceptors for O—H⋯O hydrogen bonds from adjacent water mol­ecules, generating a three-dimensional network. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008135/ /pubmed/21588539 http://dx.doi.org/10.1107/S1600536810032733 Text en © Seik Weng Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ng, Seik Weng
Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title_full Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title_fullStr Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title_full_unstemmed Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title_short Monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) N (1),O)tin(IV)
title_sort monoclinic modification of aquadi-n-butyl­bis­(pyrazine-2-carboxyl­ato-κ(2) n (1),o)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008135/
https://www.ncbi.nlm.nih.gov/pubmed/21588539
http://dx.doi.org/10.1107/S1600536810032733
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