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Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN (1)]copper(II)}
In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral w...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008138/ https://www.ncbi.nlm.nih.gov/pubmed/21588477 http://dx.doi.org/10.1107/S1600536810030187 |
Sumario: | In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H⋯π type link molecules in the crystal structure. |
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