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Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN (1)]copper(II)}
In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral w...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008138/ https://www.ncbi.nlm.nih.gov/pubmed/21588477 http://dx.doi.org/10.1107/S1600536810030187 |
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author | Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Fairuz, Zainal A. |
collection | PubMed |
description | In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H⋯π type link molecules in the crystal structure. |
format | Text |
id | pubmed-3008138 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081382010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN (1)]copper(II)} Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intramolecular N—H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C—H⋯π type link molecules in the crystal structure. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008138/ /pubmed/21588477 http://dx.doi.org/10.1107/S1600536810030187 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN (1)]copper(II)} |
title | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN
(1)]copper(II)} |
title_full | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN
(1)]copper(II)} |
title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN
(1)]copper(II)} |
title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN
(1)]copper(II)} |
title_short | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-κN
(1)]copper(II)} |
title_sort | tetra-μ-acetato-κ(8)
o:o′-bis{[n-(4-chlorophenyl)-4-methylpyridin-2-amine-κn
(1)]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008138/ https://www.ncbi.nlm.nih.gov/pubmed/21588477 http://dx.doi.org/10.1107/S1600536810030187 |
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