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Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}

In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear mol­ecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral w...

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Autores principales: Fairuz, Zainal A., Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008138/
https://www.ncbi.nlm.nih.gov/pubmed/21588477
http://dx.doi.org/10.1107/S1600536810030187
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author Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Fairuz, Zainal A.
collection PubMed
description In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear mol­ecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intra­molecular N—H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Inter­molecular inter­actions of the C—H⋯π type link mol­ecules in the crystal structure.
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spelling pubmed-30081382010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)} Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(11)ClN(2))(2)], the complete binuclear mol­ecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)°. An intra­molecular N—H⋯O hydrogen bond is present between the amino group and a carboxyl O atom. Inter­molecular inter­actions of the C—H⋯π type link mol­ecules in the crystal structure. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008138/ /pubmed/21588477 http://dx.doi.org/10.1107/S1600536810030187 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title_full Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title_fullStr Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title_full_unstemmed Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title_short Tetra-μ-acetato-κ(8) O:O′-bis­{[N-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κN (1)]copper(II)}
title_sort tetra-μ-acetato-κ(8) o:o′-bis­{[n-(4-chloro­phen­yl)-4-methyl­pyridin-2-amine-κn (1)]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008138/
https://www.ncbi.nlm.nih.gov/pubmed/21588477
http://dx.doi.org/10.1107/S1600536810030187
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