[2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate

In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl­methyl­benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl­imino­meth­yl)quinoline. The dihedral angle be...

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Detalles Bibliográficos
Autores principales: Gárate-Morales, José Luis, Hernández-Ortega, Simón, Fernández-G, Juan Manuel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008139/
https://www.ncbi.nlm.nih.gov/pubmed/21588544
http://dx.doi.org/10.1107/S1600536810033003
Descripción
Sumario:In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl­methyl­benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl­imino­meth­yl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (−) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively.

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