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[2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate
In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropylmethylbenzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyliminomethyl)quinoline. The dihedral angle be...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008139/ https://www.ncbi.nlm.nih.gov/pubmed/21588544 http://dx.doi.org/10.1107/S1600536810033003 |
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author | Gárate-Morales, José Luis Hernández-Ortega, Simón Fernández-G, Juan Manuel |
author_facet | Gárate-Morales, José Luis Hernández-Ortega, Simón Fernández-G, Juan Manuel |
author_sort | Gárate-Morales, José Luis |
collection | PubMed |
description | In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropylmethylbenzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyliminomethyl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (−) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively. |
format | Text |
id | pubmed-3008139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30081392010-12-30 [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate Gárate-Morales, José Luis Hernández-Ortega, Simón Fernández-G, Juan Manuel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropylmethylbenzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyliminomethyl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (−) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008139/ /pubmed/21588544 http://dx.doi.org/10.1107/S1600536810033003 Text en © Gárate-Morales et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gárate-Morales, José Luis Hernández-Ortega, Simón Fernández-G, Juan Manuel [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title | [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title_full | [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title_fullStr | [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title_full_unstemmed | [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title_short | [2-(sec-Butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(II) hexafluoridophosphate |
title_sort | [2-(sec-butyliminomethyl)quinoline]chlorido(η(6)-1-isopropyl-4-methylbenzene)ruthenium(ii) hexafluoridophosphate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008139/ https://www.ncbi.nlm.nih.gov/pubmed/21588544 http://dx.doi.org/10.1107/S1600536810033003 |
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