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[2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate

In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl­methyl­benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl­imino­meth­yl)quinoline. The dihedral angle be...

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Autores principales: Gárate-Morales, José Luis, Hernández-Ortega, Simón, Fernández-G, Juan Manuel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008139/
https://www.ncbi.nlm.nih.gov/pubmed/21588544
http://dx.doi.org/10.1107/S1600536810033003
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author Gárate-Morales, José Luis
Hernández-Ortega, Simón
Fernández-G, Juan Manuel
author_facet Gárate-Morales, José Luis
Hernández-Ortega, Simón
Fernández-G, Juan Manuel
author_sort Gárate-Morales, José Luis
collection PubMed
description In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl­methyl­benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl­imino­meth­yl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (−) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively.
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spelling pubmed-30081392010-12-30 [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate Gárate-Morales, José Luis Hernández-Ortega, Simón Fernández-G, Juan Manuel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl­methyl­benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl­imino­meth­yl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (−) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008139/ /pubmed/21588544 http://dx.doi.org/10.1107/S1600536810033003 Text en © Gárate-Morales et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gárate-Morales, José Luis
Hernández-Ortega, Simón
Fernández-G, Juan Manuel
[2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title_full [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title_fullStr [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title_short [2-(sec-Butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II) hexa­fluorido­phosphate
title_sort [2-(sec-butyl­imino­meth­yl)quinoline]­chlorido(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008139/
https://www.ncbi.nlm.nih.gov/pubmed/21588544
http://dx.doi.org/10.1107/S1600536810033003
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