Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)

Tris(2-chloro­benz­yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol­ecules which differ only in the position of the nitro­gen-bound H atom of the triazole ring; one mol­...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008140/
https://www.ncbi.nlm.nih.gov/pubmed/21588487
http://dx.doi.org/10.1107/S160053681003076X
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description Tris(2-chloro­benz­yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol­ecules which differ only in the position of the nitro­gen-bound H atom of the triazole ring; one mol­ecule is linked to the other mol­ecule by an N—H⋯N hydrogen bond. In the second mol­ecule, two of the chloro­benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol­ecules shows a distorted tetra­hedral SnSC(3) coordination.
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spelling pubmed-30081402010-12-30 Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Tris(2-chloro­benz­yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol­ecules which differ only in the position of the nitro­gen-bound H atom of the triazole ring; one mol­ecule is linked to the other mol­ecule by an N—H⋯N hydrogen bond. In the second mol­ecule, two of the chloro­benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol­ecules shows a distorted tetra­hedral SnSC(3) coordination. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008140/ /pubmed/21588487 http://dx.doi.org/10.1107/S160053681003076X Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title_full Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title_fullStr Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title_full_unstemmed Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title_short Tris(2-chloro­benz­yl)(1H-1,2,4-triazole-5-thiol­ato-κS)tin(IV)–tris­(2-chloro­benz­yl)(4H-1,2,4-triazole-3-thiol­ato-κS)tin(IV) (1/1)
title_sort tris(2-chloro­benz­yl)(1h-1,2,4-triazole-5-thiol­ato-κs)tin(iv)–tris­(2-chloro­benz­yl)(4h-1,2,4-triazole-3-thiol­ato-κs)tin(iv) (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008140/
https://www.ncbi.nlm.nih.gov/pubmed/21588487
http://dx.doi.org/10.1107/S160053681003076X
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