10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one

In the title compound, C(19)H(15)NO(3)S, the dihydro­phenanthrene unit is not planar, its central ring being distorted towards a sofa conformation. The essentially planar thia­zole ring [maximum deviation = 0.005 (1) Å] is inclined at a dihedral angle of 85.29 (5)° with respect to the mean plane for...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Goh, Jia Hao, Liu, Yang, Zhang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008141/
https://www.ncbi.nlm.nih.gov/pubmed/21588603
http://dx.doi.org/10.1107/S1600536810031004
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author Fun, Hoong-Kun
Goh, Jia Hao
Liu, Yang
Zhang, Yan
author_facet Fun, Hoong-Kun
Goh, Jia Hao
Liu, Yang
Zhang, Yan
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(19)H(15)NO(3)S, the dihydro­phenanthrene unit is not planar, its central ring being distorted towards a sofa conformation. The essentially planar thia­zole ring [maximum deviation = 0.005 (1) Å] is inclined at a dihedral angle of 85.29 (5)° with respect to the mean plane formed through the dihydro­phenanthrene unit. In the crystal structure, pairs of inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers. Inter­molecular O—H⋯N hydrogen bonds further inter­connect these dimers into chains along the a axis. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions involving the thia­zole ring.
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spelling pubmed-30081412010-12-30 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one Fun, Hoong-Kun Goh, Jia Hao Liu, Yang Zhang, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(15)NO(3)S, the dihydro­phenanthrene unit is not planar, its central ring being distorted towards a sofa conformation. The essentially planar thia­zole ring [maximum deviation = 0.005 (1) Å] is inclined at a dihedral angle of 85.29 (5)° with respect to the mean plane formed through the dihydro­phenanthrene unit. In the crystal structure, pairs of inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers. Inter­molecular O—H⋯N hydrogen bonds further inter­connect these dimers into chains along the a axis. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions involving the thia­zole ring. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008141/ /pubmed/21588603 http://dx.doi.org/10.1107/S1600536810031004 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Goh, Jia Hao
Liu, Yang
Zhang, Yan
10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title_full 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title_fullStr 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title_full_unstemmed 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title_short 10-(2-Eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10H)-one
title_sort 10-(2-eth­oxy-1,3-thia­zol-5-yl)-10-hy­droxy­phenanthren-9(10h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008141/
https://www.ncbi.nlm.nih.gov/pubmed/21588603
http://dx.doi.org/10.1107/S1600536810031004
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AT liuyang 102ethoxy13thiazol5yl10hydroxyphenanthren910hone
AT zhangyan 102ethoxy13thiazol5yl10hydroxyphenanthren910hone

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