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Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate
In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water molecules in a distorted octahedral geometry....
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008971/ https://www.ncbi.nlm.nih.gov/pubmed/21588898 http://dx.doi.org/10.1107/S160053681004331X |
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author | Wang, Yan-Zhi Li, Xiao-Kun Yang, Huai-Xia Zhou, Wan Meng, Xiang-Ru |
author_facet | Wang, Yan-Zhi Li, Xiao-Kun Yang, Huai-Xia Zhou, Wan Meng, Xiang-Ru |
author_sort | Wang, Yan-Zhi |
collection | PubMed |
description | In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water molecules in a distorted octahedral geometry. The sulfate tetrahedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent molecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water molecules into a three-dimensional network. |
format | Text |
id | pubmed-3008971 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30089712010-12-30 Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate Wang, Yan-Zhi Li, Xiao-Kun Yang, Huai-Xia Zhou, Wan Meng, Xiang-Ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water molecules in a distorted octahedral geometry. The sulfate tetrahedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent molecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water molecules into a three-dimensional network. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3008971/ /pubmed/21588898 http://dx.doi.org/10.1107/S160053681004331X Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yan-Zhi Li, Xiao-Kun Yang, Huai-Xia Zhou, Wan Meng, Xiang-Ru Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title | Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title_full | Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title_fullStr | Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title_full_unstemmed | Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title_short | Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatozinc(II) dihydrate |
title_sort | tetraaqua{1-[(1h-1,2,3-benzotriazol-1-yl)methyl]-1h-1,2,4-triazole}sulfatozinc(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008971/ https://www.ncbi.nlm.nih.gov/pubmed/21588898 http://dx.doi.org/10.1107/S160053681004331X |
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