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Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate

In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water mol­ecules in a distorted octa­hedral geometry....

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Detalles Bibliográficos
Autores principales: Wang, Yan-Zhi, Li, Xiao-Kun, Yang, Huai-Xia, Zhou, Wan, Meng, Xiang-Ru
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008971/
https://www.ncbi.nlm.nih.gov/pubmed/21588898
http://dx.doi.org/10.1107/S160053681004331X
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author Wang, Yan-Zhi
Li, Xiao-Kun
Yang, Huai-Xia
Zhou, Wan
Meng, Xiang-Ru
author_facet Wang, Yan-Zhi
Li, Xiao-Kun
Yang, Huai-Xia
Zhou, Wan
Meng, Xiang-Ru
author_sort Wang, Yan-Zhi
collection PubMed
description In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water mol­ecules in a distorted octa­hedral geometry. The sulfate tetra­hedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water mol­ecules into a three-dimensional network.
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spelling pubmed-30089712010-12-30 Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate Wang, Yan-Zhi Li, Xiao-Kun Yang, Huai-Xia Zhou, Wan Meng, Xiang-Ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water mol­ecules in a distorted octa­hedral geometry. The sulfate tetra­hedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water mol­ecules into a three-dimensional network. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3008971/ /pubmed/21588898 http://dx.doi.org/10.1107/S160053681004331X Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan-Zhi
Li, Xiao-Kun
Yang, Huai-Xia
Zhou, Wan
Meng, Xiang-Ru
Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title_full Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title_fullStr Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title_full_unstemmed Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title_short Tetra­aqua­{1-[(1H-1,2,3-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole}sulfato­zinc(II) dihydrate
title_sort tetra­aqua­{1-[(1h-1,2,3-benzotriazol-1-yl)meth­yl]-1h-1,2,4-triazole}sulfato­zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008971/
https://www.ncbi.nlm.nih.gov/pubmed/21588898
http://dx.doi.org/10.1107/S160053681004331X
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