Cargando…
Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3) O,N,O′}zinc(II)
In the crystal structure of the zinc(II) complex of bicine, [Zn(C(6)H(12)NO(4))(2)], the deprotonated amino acid O,N,O′-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the met...
| Autores principales: | , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008976/ https://www.ncbi.nlm.nih.gov/pubmed/21588900 http://dx.doi.org/10.1107/S1600536810043217 |
| _version_ | 1782194575572467712 |
|---|---|
| author | Lo, Kong Mun Ng, Seik Weng |
| author_facet | Lo, Kong Mun Ng, Seik Weng |
| author_sort | Lo, Kong Mun |
| collection | PubMed |
| description | In the crystal structure of the zinc(II) complex of bicine, [Zn(C(6)H(12)NO(4))(2)], the deprotonated amino acid O,N,O′-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the metal atom. The metal atom lies on a center of inversion. The uncoordinated carboxylate O atom is hydrogen bonded to the hydroxy groups of adjacent molecules, these two hydrogen bonds leading to the formation of a three-dimensional network. |
| format | Text |
| id | pubmed-3008976 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30089762010-12-30 Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3) O,N,O′}zinc(II) Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the zinc(II) complex of bicine, [Zn(C(6)H(12)NO(4))(2)], the deprotonated amino acid O,N,O′-chelates to the metal atom through a carboxylate O atom, a hydroxy O atom and the N atom, the three atoms occupying fac positions of the distorted octahedron surrounding the metal atom. The metal atom lies on a center of inversion. The uncoordinated carboxylate O atom is hydrogen bonded to the hydroxy groups of adjacent molecules, these two hydrogen bonds leading to the formation of a three-dimensional network. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3008976/ /pubmed/21588900 http://dx.doi.org/10.1107/S1600536810043217 Text en © Lo and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lo, Kong Mun Ng, Seik Weng Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3) O,N,O′}zinc(II) |
| title | Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
O,N,O′}zinc(II) |
| title_full | Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
O,N,O′}zinc(II) |
| title_fullStr | Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
O,N,O′}zinc(II) |
| title_full_unstemmed | Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
O,N,O′}zinc(II) |
| title_short | Bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
O,N,O′}zinc(II) |
| title_sort | bis{2-[bis(2-hydroxyethyl)amino]acetato-κ(3)
o,n,o′}zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008976/ https://www.ncbi.nlm.nih.gov/pubmed/21588900 http://dx.doi.org/10.1107/S1600536810043217 |
| work_keys_str_mv | AT lokongmun bis2bis2hydroxyethylaminoacetatok3onozincii AT ngseikweng bis2bis2hydroxyethylaminoacetatok3onozincii |