Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]

The asymmetric unit of the title compound, [Na(2)(C(8)H(8)O(8))](n), contains one Na(+) ion and half of a 2,3-bis(carboxymethyl)butanedioate (H(2)BTC(2−)) dianion, which lies on a center of symmetry. The dianion exhibits a μ(10)-bridging mode. Each Na atom lies in a NaO(6) octa­hedron defined by six...

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Detalles Bibliográficos
Autores principales: Wu, Jiang, Zhu, Hong-lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008981/
https://www.ncbi.nlm.nih.gov/pubmed/21588846
http://dx.doi.org/10.1107/S1600536810040857
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author Wu, Jiang
Zhu, Hong-lin
author_facet Wu, Jiang
Zhu, Hong-lin
author_sort Wu, Jiang
collection PubMed
description The asymmetric unit of the title compound, [Na(2)(C(8)H(8)O(8))](n), contains one Na(+) ion and half of a 2,3-bis(carboxymethyl)butanedioate (H(2)BTC(2−)) dianion, which lies on a center of symmetry. The dianion exhibits a μ(10)-bridging mode. Each Na atom lies in a NaO(6) octa­hedron defined by six O atoms from five dianions. Adjacent NaO(6) octa­hedra share a common O—O edge, generating a biocta­hedron; adjacent biocta­hedra are O—O edge-connected to one another, building up a chain along [001]. The chains are connected by adjacent H(2)BTC(2−) anions into a three-dimensional framework. The structure is further stabilized by O—H⋯O hydrogen bonds.
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spelling pubmed-30089812010-12-30 Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium] Wu, Jiang Zhu, Hong-lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Na(2)(C(8)H(8)O(8))](n), contains one Na(+) ion and half of a 2,3-bis(carboxymethyl)butanedioate (H(2)BTC(2−)) dianion, which lies on a center of symmetry. The dianion exhibits a μ(10)-bridging mode. Each Na atom lies in a NaO(6) octa­hedron defined by six O atoms from five dianions. Adjacent NaO(6) octa­hedra share a common O—O edge, generating a biocta­hedron; adjacent biocta­hedra are O—O edge-connected to one another, building up a chain along [001]. The chains are connected by adjacent H(2)BTC(2−) anions into a three-dimensional framework. The structure is further stabilized by O—H⋯O hydrogen bonds. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3008981/ /pubmed/21588846 http://dx.doi.org/10.1107/S1600536810040857 Text en © Wu and Zhu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Jiang
Zhu, Hong-lin
Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title_full Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title_fullStr Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title_full_unstemmed Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title_short Poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
title_sort poly[[μ(10)-2,3-bis(carboxymethyl)butanedioato]disodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008981/
https://www.ncbi.nlm.nih.gov/pubmed/21588846
http://dx.doi.org/10.1107/S1600536810040857
work_keys_str_mv AT wujiang polym1023biscarboxymethylbutanedioatodisodium
AT zhuhonglin polym1023biscarboxymethylbutanedioatodisodium

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