catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]

The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The d...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008982/
https://www.ncbi.nlm.nih.gov/pubmed/21588895
http://dx.doi.org/10.1107/S1600536810042807
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra­hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra­zine ligand and one terminal triphenyl­phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter­action.
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spelling pubmed-30089822010-12-30 catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cu(2)I(2)(C(12)H(8)N(6))(C(18)H(15)P)(2)]·2CH(3)CN}(n), contains centrosymmetric dinuclear Cu(2)I(2)(PPh(3))(2) units bridged by 3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine ligands lying also across crystallographic inversion centers, giving a chain structure in the ab plane. The distorted tetra­hedral Cu(I) atoms in the dinuclear unit are coordinated by two bridging iodide anions, one pyridine N atom from the substituted tetra­zine ligand and one terminal triphenyl­phosphine P-atom donor. The Cu⋯Cu distance is 2.8293 (12) Å, implying a weak Cu⋯Cu inter­action. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3008982/ /pubmed/21588895 http://dx.doi.org/10.1107/S1600536810042807 Text en © Jinfang Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title_full catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title_fullStr catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title_full_unstemmed catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title_short catena-Poly[[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
title_sort catena-poly[[[(triphenyl­phosphane)copper(i)]-di-μ-iodido-[(triphenyl­phosphane)copper(i)]-μ-[3,6-bis­(4-pyrid­yl)-1,2,4,5-tetra­zine]] acetonitrile disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008982/
https://www.ncbi.nlm.nih.gov/pubmed/21588895
http://dx.doi.org/10.1107/S1600536810042807
work_keys_str_mv AT zhangjinfang catenapolytriphenylphosphanecopperidimiodidotriphenylphosphanecopperim36bis4pyridyl1245tetrazineacetonitriledisolvate

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