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2-Amino-5-methylpyridinium 1H-pyrazole-3,5-dicarboxylate trihydrate
In the title compound, 2C(6)H(9)N(2) (+)·C(5)H(2)N(2)O(4) (2−)·3H(2)O, the 1H-pyrazole-3,5-dicarboxylate anion is close to planar [maximum deviation = 0.208 (1) Å]. The two distinct 2-amino-5-methylpyridinium cations are also almost planar, with maximum deviations of 0.018 (2) and 0.014 (2) Å. In...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008987/ https://www.ncbi.nlm.nih.gov/pubmed/21589058 http://dx.doi.org/10.1107/S1600536810041644 |
Sumario: | In the title compound, 2C(6)H(9)N(2) (+)·C(5)H(2)N(2)O(4) (2−)·3H(2)O, the 1H-pyrazole-3,5-dicarboxylate anion is close to planar [maximum deviation = 0.208 (1) Å]. The two distinct 2-amino-5-methylpyridinium cations are also almost planar, with maximum deviations of 0.018 (2) and 0.014 (2) Å. In the crystal, pairs of intermolecular N—H⋯O and O—H⋯O hydrogen bonds connect neighbouring molecules into dimers, generating R (2) (2)(8) and R (2) (4)(8) ring motifs, respectively. Further intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
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