(Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate

In the title compound, [AuFe(C(5)H(5))(C(5)H(5)O(2)PS)(C(18)H(15)P)]·CH(2)Cl(2), the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P—Au—S bond angle of 176.81 (6)°. The difference in P=O and P—O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, i...

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Autores principales: van der Walt, Hendriette, Muller, Alfred, Staples, Richard J., Van Zyl, Werner E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008988/
https://www.ncbi.nlm.nih.gov/pubmed/21588806
http://dx.doi.org/10.1107/S1600536810039255
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author van der Walt, Hendriette
Muller, Alfred
Staples, Richard J.
Van Zyl, Werner E.
author_facet van der Walt, Hendriette
Muller, Alfred
Staples, Richard J.
Van Zyl, Werner E.
author_sort van der Walt, Hendriette
collection PubMed
description In the title compound, [AuFe(C(5)H(5))(C(5)H(5)O(2)PS)(C(18)H(15)P)]·CH(2)Cl(2), the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P—Au—S bond angle of 176.81 (6)°. The difference in P=O and P—O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P—O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link dinuclear mol­ecules into chains propagated in the [010] direction. The dichloro­methane solvent mol­ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.
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spelling pubmed-30089882010-12-30 (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate van der Walt, Hendriette Muller, Alfred Staples, Richard J. Van Zyl, Werner E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [AuFe(C(5)H(5))(C(5)H(5)O(2)PS)(C(18)H(15)P)]·CH(2)Cl(2), the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P—Au—S bond angle of 176.81 (6)°. The difference in P=O and P—O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P—O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link dinuclear mol­ecules into chains propagated in the [010] direction. The dichloro­methane solvent mol­ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3008988/ /pubmed/21588806 http://dx.doi.org/10.1107/S1600536810039255 Text en © van der Walt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van der Walt, Hendriette
Muller, Alfred
Staples, Richard J.
Van Zyl, Werner E.
(Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title_full (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title_fullStr (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title_full_unstemmed (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title_short (Ferrocenyl­thio­phospho­nato-κS)(triphenyl­phosphane-κP)gold(I) dichloro­methane monosolvate
title_sort (ferrocenyl­thio­phospho­nato-κs)(triphenyl­phosphane-κp)gold(i) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008988/
https://www.ncbi.nlm.nih.gov/pubmed/21588806
http://dx.doi.org/10.1107/S1600536810039255
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AT mulleralfred ferrocenylthiophosphonatokstriphenylphosphanekpgoldidichloromethanemonosolvate
AT staplesrichardj ferrocenylthiophosphonatokstriphenylphosphanekpgoldidichloromethanemonosolvate
AT vanzylwernere ferrocenylthiophosphonatokstriphenylphosphanekpgoldidichloromethanemonosolvate

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