catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]

In the title compound, [Pb(C(10)H(11)O(2))(2)](n) or [Pb(hino)(2)](n), the lead(II) ion is chelated by two hinokitiolate ligands in a distorted square-pyramidal configuration, with Pb—O bond lengths in the range 2.327 (6)–2.479 (9) Å. The 6s (2) lone electron pair of the lead(II) ion becomes stereoc...

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Detalles Bibliográficos
Autores principales: Lyczko, Krzysztof, Lyczko, Monika, Starosta, Wojciech
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008991/
https://www.ncbi.nlm.nih.gov/pubmed/21588830
http://dx.doi.org/10.1107/S1600536810039978
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author Lyczko, Krzysztof
Lyczko, Monika
Starosta, Wojciech
author_facet Lyczko, Krzysztof
Lyczko, Monika
Starosta, Wojciech
author_sort Lyczko, Krzysztof
collection PubMed
description In the title compound, [Pb(C(10)H(11)O(2))(2)](n) or [Pb(hino)(2)](n), the lead(II) ion is chelated by two hinokitiolate ligands in a distorted square-pyramidal configuration, with Pb—O bond lengths in the range 2.327 (6)–2.479 (9) Å. The 6s (2) lone electron pair of the lead(II) ion becomes stereochemically active and is directed towards the apex of this pyramid. The crystal structure of the title compound consists of chains formed by the bis­(hinokitiolato)lead(II) mol­ecules situated along the twofold screw axis. The coordination sphere around the lead(II) ion is completed by three additional O atoms, at 2.625 (7), 3.016 (8) and 3.064 (8) Å, from the two neighbouring Pb(hino)(2) units. Both isopropyl groups are rotationally disordered.
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spelling pubmed-30089912010-12-30 catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)] Lyczko, Krzysztof Lyczko, Monika Starosta, Wojciech Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(10)H(11)O(2))(2)](n) or [Pb(hino)(2)](n), the lead(II) ion is chelated by two hinokitiolate ligands in a distorted square-pyramidal configuration, with Pb—O bond lengths in the range 2.327 (6)–2.479 (9) Å. The 6s (2) lone electron pair of the lead(II) ion becomes stereochemically active and is directed towards the apex of this pyramid. The crystal structure of the title compound consists of chains formed by the bis­(hinokitiolato)lead(II) mol­ecules situated along the twofold screw axis. The coordination sphere around the lead(II) ion is completed by three additional O atoms, at 2.625 (7), 3.016 (8) and 3.064 (8) Å, from the two neighbouring Pb(hino)(2) units. Both isopropyl groups are rotationally disordered. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3008991/ /pubmed/21588830 http://dx.doi.org/10.1107/S1600536810039978 Text en © Lyczko et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lyczko, Krzysztof
Lyczko, Monika
Starosta, Wojciech
catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title_full catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title_fullStr catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title_full_unstemmed catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title_short catena-Poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(II)]
title_sort catena-poly[(μ(3)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)(μ(2)-2-hy­droxy-4-isopropyl­cyclo­hepta-2,4,6-trien-1-onato)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008991/
https://www.ncbi.nlm.nih.gov/pubmed/21588830
http://dx.doi.org/10.1107/S1600536810039978
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AT lyczkomonika catenapolym32hydroxy4isopropylcyclohepta246trien1onatom22hydroxy4isopropylcyclohepta246trien1onatoleadii
AT starostawojciech catenapolym32hydroxy4isopropylcyclohepta246trien1onatom22hydroxy4isopropylcyclohepta246trien1onatoleadii

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