Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)

The mol­ecular structure of the neutral mononuclear title complex, [Ni(C(17)H(12)ClN(2)O(2))(2)(CH(3)OH)(2)], is centrosymmetric. The Ni(II) atom, which is located on an inversion center, is in a distorted octahedral coordination, defined by four O atoms from two ligands as well as two O atoms from...

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Detalles Bibliográficos
Autores principales: Zhang, Xin, Huang, Meng, Du, Cong, Han, Junjing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008993/
https://www.ncbi.nlm.nih.gov/pubmed/21588804
http://dx.doi.org/10.1107/S1600536810038973
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author Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
author_facet Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
author_sort Zhang, Xin
collection PubMed
description The mol­ecular structure of the neutral mononuclear title complex, [Ni(C(17)H(12)ClN(2)O(2))(2)(CH(3)OH)(2)], is centrosymmetric. The Ni(II) atom, which is located on an inversion center, is in a distorted octahedral coordination, defined by four O atoms from two ligands as well as two O atoms from two methanol mol­ecules. Inter­molecular O—H⋯N hydrogen bonds between the hy­droxy group of methanol and a pyrazole N atom link the mol­ecules, forming a two-dimensional network parallel to (100).
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spelling pubmed-30089932010-12-30 Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II) Zhang, Xin Huang, Meng Du, Cong Han, Junjing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the neutral mononuclear title complex, [Ni(C(17)H(12)ClN(2)O(2))(2)(CH(3)OH)(2)], is centrosymmetric. The Ni(II) atom, which is located on an inversion center, is in a distorted octahedral coordination, defined by four O atoms from two ligands as well as two O atoms from two methanol mol­ecules. Inter­molecular O—H⋯N hydrogen bonds between the hy­droxy group of methanol and a pyrazole N atom link the mol­ecules, forming a two-dimensional network parallel to (100). International Union of Crystallography 2010-10-09 /pmc/articles/PMC3008993/ /pubmed/21588804 http://dx.doi.org/10.1107/S1600536810038973 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xin
Huang, Meng
Du, Cong
Han, Junjing
Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title_full Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title_fullStr Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title_full_unstemmed Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title_short Bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ(2) O,O′]bis­(methanol-κO)nickel(II)
title_sort bis[4-(4-chloro­benzo­yl)-3-methyl-1-phenyl-1h-pyrazol-5-olato-κ(2) o,o′]bis­(methanol-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008993/
https://www.ncbi.nlm.nih.gov/pubmed/21588804
http://dx.doi.org/10.1107/S1600536810038973
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AT ducong bis44chlorobenzoyl3methyl1phenyl1hpyrazol5olatok2oobismethanolkonickelii
AT hanjunjing bis44chlorobenzoyl3methyl1phenyl1hpyrazol5olatok2oobismethanolkonickelii

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