Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate

In the title compound, C(11)H(12)N(2)S(2), the dithio­carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl­idene group. The atoms of the propenyl­idene and dithio­carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl...

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Autores principales: Tarafder, M. T. H., Khan, Sultana Shakila, Islam, M. A. A. A. A., Lorenzi, Lea, Zangrando, Ennio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008995/
https://www.ncbi.nlm.nih.gov/pubmed/21589036
http://dx.doi.org/10.1107/S1600536810041115
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author Tarafder, M. T. H.
Khan, Sultana Shakila
Islam, M. A. A. A. A.
Lorenzi, Lea
Zangrando, Ennio
author_facet Tarafder, M. T. H.
Khan, Sultana Shakila
Islam, M. A. A. A. A.
Lorenzi, Lea
Zangrando, Ennio
author_sort Tarafder, M. T. H.
collection PubMed
description In the title compound, C(11)H(12)N(2)S(2), the dithio­carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl­idene group. The atoms of the propenyl­idene and dithio­carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol­ecules form inversion dimers via pairs of N—H⋯S hydrogen bonds involving the terminal S atom.
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spelling pubmed-30089952010-12-30 Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate Tarafder, M. T. H. Khan, Sultana Shakila Islam, M. A. A. A. A. Lorenzi, Lea Zangrando, Ennio Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(12)N(2)S(2), the dithio­carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl­idene group. The atoms of the propenyl­idene and dithio­carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol­ecules form inversion dimers via pairs of N—H⋯S hydrogen bonds involving the terminal S atom. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3008995/ /pubmed/21589036 http://dx.doi.org/10.1107/S1600536810041115 Text en © Tarafder et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tarafder, M. T. H.
Khan, Sultana Shakila
Islam, M. A. A. A. A.
Lorenzi, Lea
Zangrando, Ennio
Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_full Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_fullStr Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_full_unstemmed Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_short Methyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_sort methyl 3-[(e,e)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008995/
https://www.ncbi.nlm.nih.gov/pubmed/21589036
http://dx.doi.org/10.1107/S1600536810041115
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