Cargando…
μ-Cyanido-1:2κ(2) N:C-tricyanido-2κ(3) C-(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1κ(4) N,N′,N′′,N′′′)dinickel(II) N,N-dimethylformamide monosolvate hemihydrate
The two Ni(II) atoms in the title complex, [Ni(2)(CN)(4)(C(16)H(36)N(4))]·C(3)H(7)NO·0.5H(2)O, are bridged by a cyanide ion. The macrocycle folds around one Ni(II) atom, which is five-coordinated in an NiN(5) square-pyramidal geometry. The other Ni(II) atom is surrounded by the cyanide ions in an Ni...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008996/ https://www.ncbi.nlm.nih.gov/pubmed/21588884 http://dx.doi.org/10.1107/S1600536810042625 |