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[2,2′-Dihydroxy-N (2),N (2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II)
The Cu(II) atom in the title complex, [Cu(C(19)H(17)N(5)O(5))], is coordinated by two N atoms and two O atoms of one 2,2′-dihydroxy-N (2),N (2)’-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidate ligand, exhibiting a distorted square-planar geometry. The dihedral angle between the two benzene...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008999/ https://www.ncbi.nlm.nih.gov/pubmed/21588849 http://dx.doi.org/10.1107/S1600536810040754 |
Sumario: | The Cu(II) atom in the title complex, [Cu(C(19)H(17)N(5)O(5))], is coordinated by two N atoms and two O atoms of one 2,2′-dihydroxy-N (2),N (2)’-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidate ligand, exhibiting a distorted square-planar geometry. The dihedral angle between the two benzene rings in the oxime hydrazone is 7.62 (15)°. The molecular configuration is stabilized by intramolecular O—H⋯N hydrogen bonds. Pairs of centrosymmetrically related molecules are linked into dimers by two intermolecular C—H⋯O hydrogen bonds. Each dimer is further connected to four neighboring dimers via four O—H⋯O hydrogen bonds, forming an extended two-dimensional structure. The oxime O atom is disordered over two orientations in a 2:1 ratio. |
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