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[2,2′-Dihydroxy-N (2),N (2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II)
The Cu(II) atom in the title complex, [Cu(C(19)H(17)N(5)O(5))], is coordinated by two N atoms and two O atoms of one 2,2′-dihydroxy-N (2),N (2)’-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidate ligand, exhibiting a distorted square-planar geometry. The dihedral angle between the two benzene...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008999/ https://www.ncbi.nlm.nih.gov/pubmed/21588849 http://dx.doi.org/10.1107/S1600536810040754 |
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author | Xiao, Zi-Jing |
author_facet | Xiao, Zi-Jing |
author_sort | Xiao, Zi-Jing |
collection | PubMed |
description | The Cu(II) atom in the title complex, [Cu(C(19)H(17)N(5)O(5))], is coordinated by two N atoms and two O atoms of one 2,2′-dihydroxy-N (2),N (2)’-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidate ligand, exhibiting a distorted square-planar geometry. The dihedral angle between the two benzene rings in the oxime hydrazone is 7.62 (15)°. The molecular configuration is stabilized by intramolecular O—H⋯N hydrogen bonds. Pairs of centrosymmetrically related molecules are linked into dimers by two intermolecular C—H⋯O hydrogen bonds. Each dimer is further connected to four neighboring dimers via four O—H⋯O hydrogen bonds, forming an extended two-dimensional structure. The oxime O atom is disordered over two orientations in a 2:1 ratio. |
format | Text |
id | pubmed-3008999 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30089992010-12-30 [2,2′-Dihydroxy-N (2),N (2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) Xiao, Zi-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) atom in the title complex, [Cu(C(19)H(17)N(5)O(5))], is coordinated by two N atoms and two O atoms of one 2,2′-dihydroxy-N (2),N (2)’-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidate ligand, exhibiting a distorted square-planar geometry. The dihedral angle between the two benzene rings in the oxime hydrazone is 7.62 (15)°. The molecular configuration is stabilized by intramolecular O—H⋯N hydrogen bonds. Pairs of centrosymmetrically related molecules are linked into dimers by two intermolecular C—H⋯O hydrogen bonds. Each dimer is further connected to four neighboring dimers via four O—H⋯O hydrogen bonds, forming an extended two-dimensional structure. The oxime O atom is disordered over two orientations in a 2:1 ratio. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3008999/ /pubmed/21588849 http://dx.doi.org/10.1107/S1600536810040754 Text en © Zi-Jing Xiao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xiao, Zi-Jing [2,2′-Dihydroxy-N (2),N (2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title | [2,2′-Dihydroxy-N
(2),N
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title_full | [2,2′-Dihydroxy-N
(2),N
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title_fullStr | [2,2′-Dihydroxy-N
(2),N
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title_full_unstemmed | [2,2′-Dihydroxy-N
(2),N
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title_short | [2,2′-Dihydroxy-N
(2),N
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(II) |
title_sort | [2,2′-dihydroxy-n
(2),n
(2′)-(3-hydroxyiminopentane-2,4-diyl)dibenzohydrazidato]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008999/ https://www.ncbi.nlm.nih.gov/pubmed/21588849 http://dx.doi.org/10.1107/S1600536810040754 |
work_keys_str_mv | AT xiaozijing 22dihydroxyn2n23hydroxyiminopentane24diyldibenzohydrazidatocopperii |