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4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one
The title compound, C(26)H(24)N(2)O(2), was prepared from the reaction of 4-chloro-3-formylcoumarin with p-methylbenzylamine. Even though there are no strong and specific interactions in the crystal structure, the translationally related molecules form chains along the b axis. The coumarin moie...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009000/ https://www.ncbi.nlm.nih.gov/pubmed/21589052 http://dx.doi.org/10.1107/S1600536810041218 |
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author | Rambabu, D. Rama Krishna, G. Malla Reddy, C. Pal, Manojit |
author_facet | Rambabu, D. Rama Krishna, G. Malla Reddy, C. Pal, Manojit |
author_sort | Rambabu, D. |
collection | PubMed |
description | The title compound, C(26)H(24)N(2)O(2), was prepared from the reaction of 4-chloro-3-formylcoumarin with p-methylbenzylamine. Even though there are no strong and specific interactions in the crystal structure, the translationally related molecules form chains along the b axis. The coumarin moieties are stacked through π–π interactions [centroid–centroid distance = 3.5275 (7) Å], forming layers perpendicular to the stacking direction. |
format | Text |
id | pubmed-3009000 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090002010-12-30 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one Rambabu, D. Rama Krishna, G. Malla Reddy, C. Pal, Manojit Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(24)N(2)O(2), was prepared from the reaction of 4-chloro-3-formylcoumarin with p-methylbenzylamine. Even though there are no strong and specific interactions in the crystal structure, the translationally related molecules form chains along the b axis. The coumarin moieties are stacked through π–π interactions [centroid–centroid distance = 3.5275 (7) Å], forming layers perpendicular to the stacking direction. International Union of Crystallography 2010-10-20 /pmc/articles/PMC3009000/ /pubmed/21589052 http://dx.doi.org/10.1107/S1600536810041218 Text en © Rambabu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Rambabu, D. Rama Krishna, G. Malla Reddy, C. Pal, Manojit 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title | 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title_full | 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title_fullStr | 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title_full_unstemmed | 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title_short | 4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one |
title_sort | 4-[(4-methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009000/ https://www.ncbi.nlm.nih.gov/pubmed/21589052 http://dx.doi.org/10.1107/S1600536810041218 |
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