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7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol

In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The mol­ecule has a Z configuration about the C=N bond....

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Detalles Bibliográficos
Autores principales: Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009002/
https://www.ncbi.nlm.nih.gov/pubmed/21588945
http://dx.doi.org/10.1107/S1600536810039358
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author Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Nagasawa, Atsushi
collection PubMed
description In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are connected by a pair of inter­molecular O—H⋯O hydrogen bonds between the hy­droxy and the nitro group, forming centrosymmetric dimers. Inter­molecular C—H⋯O inter­actions also occur.
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spelling pubmed-30090022010-12-30 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are connected by a pair of inter­molecular O—H⋯O hydrogen bonds between the hy­droxy and the nitro group, forming centrosymmetric dimers. Inter­molecular C—H⋯O inter­actions also occur. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009002/ /pubmed/21588945 http://dx.doi.org/10.1107/S1600536810039358 Text en © Nagasawa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title_full 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title_fullStr 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title_full_unstemmed 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title_short 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
title_sort 7-methoxy-1-{[(z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009002/
https://www.ncbi.nlm.nih.gov/pubmed/21588945
http://dx.doi.org/10.1107/S1600536810039358
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