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7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol
In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The molecule has a Z configuration about the C=N bond....
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009002/ https://www.ncbi.nlm.nih.gov/pubmed/21588945 http://dx.doi.org/10.1107/S1600536810039358 |
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author | Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki |
author_facet | Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki |
author_sort | Nagasawa, Atsushi |
collection | PubMed |
description | In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The molecule has a Z configuration about the C=N bond. In the crystal, molecules are connected by a pair of intermolecular O—H⋯O hydrogen bonds between the hydroxy and the nitro group, forming centrosymmetric dimers. Intermolecular C—H⋯O interactions also occur. |
format | Text |
id | pubmed-3009002 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090022010-12-30 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(18)N(2)O(4), the phenyl and benzene rings are both oriented almost perpendicular to the naphthalene ring system at dihedral angles of 70.97 (5) and 84.64 (5)°. The former rings make a dihedral angle of 87.15 (6)°. The molecule has a Z configuration about the C=N bond. In the crystal, molecules are connected by a pair of intermolecular O—H⋯O hydrogen bonds between the hydroxy and the nitro group, forming centrosymmetric dimers. Intermolecular C—H⋯O interactions also occur. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009002/ /pubmed/21588945 http://dx.doi.org/10.1107/S1600536810039358 Text en © Nagasawa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title | 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title_full | 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title_fullStr | 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title_full_unstemmed | 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title_short | 7-Methoxy-1-{[(Z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
title_sort | 7-methoxy-1-{[(z)-3-nitrophenylimino](phenyl)methyl}-2-naphthol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009002/ https://www.ncbi.nlm.nih.gov/pubmed/21588945 http://dx.doi.org/10.1107/S1600536810039358 |
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