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Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[bis(2-methyl-1H-benzimidazole-κN (3))(thiocyanato-κN)cadmium(II)]
The title compound, [Cd(2)(NCS)(4)(C(8)H(8)N(2))(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyr...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009005/ https://www.ncbi.nlm.nih.gov/pubmed/21588881 http://dx.doi.org/10.1107/S1600536810042443 |
| _version_ | 1782194582676570112 |
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| author | A. Shaker, Shayma Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | A. Shaker, Shayma Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | A. Shaker, Shayma |
| collection | PubMed |
| description | The title compound, [Cd(2)(NCS)(4)(C(8)H(8)N(2))(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N—H⋯S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) Å, indicative of a π–π interaction. |
| format | Text |
| id | pubmed-3009005 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30090052010-12-30 Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[bis(2-methyl-1H-benzimidazole-κN (3))(thiocyanato-κN)cadmium(II)] A. Shaker, Shayma Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)(NCS)(4)(C(8)H(8)N(2))(4)], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N—H⋯S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) Å, indicative of a π–π interaction. International Union of Crystallography 2010-10-23 /pmc/articles/PMC3009005/ /pubmed/21588881 http://dx.doi.org/10.1107/S1600536810042443 Text en © A. Shaker et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers A. Shaker, Shayma Khaledi, Hamid Mohd Ali, Hapipah Di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[bis(2-methyl-1H-benzimidazole-κN (3))(thiocyanato-κN)cadmium(II)] |
| title | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[bis(2-methyl-1H-benzimidazole-κN
(3))(thiocyanato-κN)cadmium(II)] |
| title_full | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[bis(2-methyl-1H-benzimidazole-κN
(3))(thiocyanato-κN)cadmium(II)] |
| title_fullStr | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[bis(2-methyl-1H-benzimidazole-κN
(3))(thiocyanato-κN)cadmium(II)] |
| title_full_unstemmed | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[bis(2-methyl-1H-benzimidazole-κN
(3))(thiocyanato-κN)cadmium(II)] |
| title_short | Di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[bis(2-methyl-1H-benzimidazole-κN
(3))(thiocyanato-κN)cadmium(II)] |
| title_sort | di-μ-thiocyanato-κ(2)
n:s;κ(2)
s:n-bis[bis(2-methyl-1h-benzimidazole-κn
(3))(thiocyanato-κn)cadmium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009005/ https://www.ncbi.nlm.nih.gov/pubmed/21588881 http://dx.doi.org/10.1107/S1600536810042443 |
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