[Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)

The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 80.27 (1)°.

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009008/
https://www.ncbi.nlm.nih.gov/pubmed/21588907
http://dx.doi.org/10.1107/S1600536810043679
_version_ 1782194583409524736
author Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peulecke, Normen
collection PubMed
description The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 80.27 (1)°.
format Text
id pubmed-3009008
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30090082010-12-30 [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0) Peulecke, Normen Peitz, Stephan Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa­hedral, with a P—Cr—P bite angle of 80.27 (1)°. International Union of Crystallography 2010-10-31 /pmc/articles/PMC3009008/ /pubmed/21588907 http://dx.doi.org/10.1107/S1600536810043679 Text en © Peulecke et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
[Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title_full [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title_fullStr [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title_full_unstemmed [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title_short [Bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) P,P′]tetra­carbonyl­chromium(0)
title_sort [bis(diphenyl­phosphan­yl)dimethyl­silane-κ(2) p,p′]tetra­carbonyl­chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009008/
https://www.ncbi.nlm.nih.gov/pubmed/21588907
http://dx.doi.org/10.1107/S1600536810043679
work_keys_str_mv AT peuleckenormen bisdiphenylphosphanyldimethylsilanek2pptetracarbonylchromium0
AT peitzstephan bisdiphenylphosphanyldimethylsilanek2pptetracarbonylchromium0
AT mullerberndh bisdiphenylphosphanyldimethylsilanek2pptetracarbonylchromium0
AT spannenberganke bisdiphenylphosphanyldimethylsilanek2pptetracarbonylchromium0
AT rosenthaluwe bisdiphenylphosphanyldimethylsilanek2pptetracarbonylchromium0

Ejemplares similares