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[Bis(diphenylphosphanyl)dimethylsilane-κ(2) P,P′]tetracarbonylchromium(0)
The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octahedral, with a P—Cr—P bite angle of 80.27 (1)°.
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009008/ https://www.ncbi.nlm.nih.gov/pubmed/21588907 http://dx.doi.org/10.1107/S1600536810043679 |