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Chloridodimethyl(thiosemicarbazide)tin(IV) chloride
In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, molecules are linked by i...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009011/ https://www.ncbi.nlm.nih.gov/pubmed/21588798 http://dx.doi.org/10.1107/S1600536810038705 |
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| author | Cortes C., Laura Burgos C., Ana E. Okio, Coco K. Y. A. |
| author_facet | Cortes C., Laura Burgos C., Ana E. Okio, Coco K. Y. A. |
| author_sort | Cortes C., Laura |
| collection | PubMed |
| description | In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, molecules are linked by intermolecular N—H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N—H⋯ Cl hydrogen bonds with graph-set motif D(2) and D (3) (3)(10) link cations and anions. |
| format | Text |
| id | pubmed-3009011 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30090112010-12-30 Chloridodimethyl(thiosemicarbazide)tin(IV) chloride Cortes C., Laura Burgos C., Ana E. Okio, Coco K. Y. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, molecules are linked by intermolecular N—H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N—H⋯ Cl hydrogen bonds with graph-set motif D(2) and D (3) (3)(10) link cations and anions. International Union of Crystallography 2010-10-02 /pmc/articles/PMC3009011/ /pubmed/21588798 http://dx.doi.org/10.1107/S1600536810038705 Text en © Cortes C. et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cortes C., Laura Burgos C., Ana E. Okio, Coco K. Y. A. Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title | Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title_full | Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title_fullStr | Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title_full_unstemmed | Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title_short | Chloridodimethyl(thiosemicarbazide)tin(IV) chloride |
| title_sort | chloridodimethyl(thiosemicarbazide)tin(iv) chloride |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009011/ https://www.ncbi.nlm.nih.gov/pubmed/21588798 http://dx.doi.org/10.1107/S1600536810038705 |
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