9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.987 (2) Å], and neighboring cations and anions via C—H⋯O and C—F⋯π inter­actions. The acridine ring system and benzene ring are...

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Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009014/
https://www.ncbi.nlm.nih.gov/pubmed/21588972
http://dx.doi.org/10.1107/S1600536810039541
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author Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.987 (2) Å], and neighboring cations and anions via C—H⋯O and C—F⋯π inter­actions. The acridine ring system and benzene ring are oriented at a dihedral angle of 1.0 (1)° while the carboxyl group is twisted at an angle of 85.0 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 78.2 (1)° in the crystal structure.
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spelling pubmed-30090142010-12-30 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.987 (2) Å], and neighboring cations and anions via C—H⋯O and C—F⋯π inter­actions. The acridine ring system and benzene ring are oriented at a dihedral angle of 1.0 (1)° while the carboxyl group is twisted at an angle of 85.0 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are either parallel or inclined at an angle of 78.2 (1)° in the crystal structure. International Union of Crystallography 2010-10-09 /pmc/articles/PMC3009014/ /pubmed/21588972 http://dx.doi.org/10.1107/S1600536810039541 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(4-Chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(4-chloro­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009014/
https://www.ncbi.nlm.nih.gov/pubmed/21588972
http://dx.doi.org/10.1107/S1600536810039541
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AT krzyminskikarol 94chlorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 94chlorophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate

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