[meso-Tetra­kis(4-heptyl­oxyphen­yl)porphyrinato]nickel(II)

In the title compound, [Ni(C(72)H(84)N(4)O(4))], the four-coordinate Ni(II) ion in the middle of the planar 24-membered porphyrin ring is located on a crystallograpic inversion center, with Ni—N distances of 1.946 (2)–1.951 (2) Å. The 4-heptyl­oxyphenyl groups are twisted with respect to the porphyr...

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Detalles Bibliográficos
Autores principales: Chen, Liang, Zhao, Hong-Bin, Xie, Yu-Jia, Yang, De-Liang, Wang, Bang-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009015/
https://www.ncbi.nlm.nih.gov/pubmed/21588873
http://dx.doi.org/10.1107/S1600536810041942
Descripción
Sumario:In the title compound, [Ni(C(72)H(84)N(4)O(4))], the four-coordinate Ni(II) ion in the middle of the planar 24-membered porphyrin ring is located on a crystallograpic inversion center, with Ni—N distances of 1.946 (2)–1.951 (2) Å. The 4-heptyl­oxyphenyl groups are twisted with respect to the porphyrin mean plane, the dihedral angles being 88.5 (3) and 79.1 (2)°.

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