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Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)

In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Nei...

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Detalles Bibliográficos
Autores principales: Kubono, Koji, Tsuno, Yuki, Tani, Keita, Yokoi, Kunihiko
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009016/
https://www.ncbi.nlm.nih.gov/pubmed/21588831
http://dx.doi.org/10.1107/S1600536810040080
Descripción
Sumario:In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Neighbouring complexes are associated through inter­molecular O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis.