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Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)

In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Nei...

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Detalles Bibliográficos
Autores principales: Kubono, Koji, Tsuno, Yuki, Tani, Keita, Yokoi, Kunihiko
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009016/
https://www.ncbi.nlm.nih.gov/pubmed/21588831
http://dx.doi.org/10.1107/S1600536810040080
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author Kubono, Koji
Tsuno, Yuki
Tani, Keita
Yokoi, Kunihiko
author_facet Kubono, Koji
Tsuno, Yuki
Tani, Keita
Yokoi, Kunihiko
author_sort Kubono, Koji
collection PubMed
description In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Neighbouring complexes are associated through inter­molecular O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis.
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spelling pubmed-30090162010-12-30 Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II) Kubono, Koji Tsuno, Yuki Tani, Keita Yokoi, Kunihiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetra­dentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water mol­ecule. Neighbouring complexes are associated through inter­molecular O—H⋯O and O—H⋯F hydrogen bonds between the water mol­ecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional inter­molecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009016/ /pubmed/21588831 http://dx.doi.org/10.1107/S1600536810040080 Text en © Kubono et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kubono, Koji
Tsuno, Yuki
Tani, Keita
Yokoi, Kunihiko
Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title_full Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title_fullStr Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title_full_unstemmed Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title_short Aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(II)
title_sort aqua­{4,4′,6,6′-tetra­fluoro-2,2′-[(piperazine-1,4-di­yl)dimethyl­ene]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009016/
https://www.ncbi.nlm.nih.gov/pubmed/21588831
http://dx.doi.org/10.1107/S1600536810040080
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