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Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II)
In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Nei...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009016/ https://www.ncbi.nlm.nih.gov/pubmed/21588831 http://dx.doi.org/10.1107/S1600536810040080 |
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author | Kubono, Koji Tsuno, Yuki Tani, Keita Yokoi, Kunihiko |
author_facet | Kubono, Koji Tsuno, Yuki Tani, Keita Yokoi, Kunihiko |
author_sort | Kubono, Koji |
collection | PubMed |
description | In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H⋯O and O—H⋯F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis. |
format | Text |
id | pubmed-3009016 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090162010-12-30 Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) Kubono, Koji Tsuno, Yuki Tani, Keita Yokoi, Kunihiko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(18)H(16)F(4)N(2)O(2))(H(2)O)], the Cu(II) atom shows a distorted square-pyramidal coordination geometry with the N,N′,O,O′-tetradentate piperazine–diphenolate ligand forming the basal plane. The apical site is occupied by the O atom of a coordinated water molecule. Neighbouring complexes are associated through intermolecular O—H⋯O and O—H⋯F hydrogen bonds between the water molecule and a phenolate O atom or an F atom from an adjacent ligand, respectively, forming a centrosymmetric dimer. Dimers are linked by additional intermolecular C—H⋯O and C—H⋯F hydrogen bonds, giving infinite chains propagating along the a axis. International Union of Crystallography 2010-10-13 /pmc/articles/PMC3009016/ /pubmed/21588831 http://dx.doi.org/10.1107/S1600536810040080 Text en © Kubono et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kubono, Koji Tsuno, Yuki Tani, Keita Yokoi, Kunihiko Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title | Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title_full | Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title_fullStr | Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title_full_unstemmed | Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title_short | Aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(II) |
title_sort | aqua{4,4′,6,6′-tetrafluoro-2,2′-[(piperazine-1,4-diyl)dimethylene]diphenolato}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009016/ https://www.ncbi.nlm.nih.gov/pubmed/21588831 http://dx.doi.org/10.1107/S1600536810040080 |
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