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catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
Hexamethylphosphoramide (hmp), tetrathiomolybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009021/ https://www.ncbi.nlm.nih.gov/pubmed/21588894 http://dx.doi.org/10.1107/S1600536810042728 |
Sumario: | Hexamethylphosphoramide (hmp), tetrathiomolybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-antiprismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue. |
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