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catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]

Hexamethyl­phospho­ramide (hmp), tetra­thio­molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009021/
https://www.ncbi.nlm.nih.gov/pubmed/21588894
http://dx.doi.org/10.1107/S1600536810042728
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description Hexamethyl­phospho­ramide (hmp), tetra­thio­molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti­prismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue.
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spelling pubmed-30090212010-12-30 catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hexamethyl­phospho­ramide (hmp), tetra­thio­molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti­prismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009021/ /pubmed/21588894 http://dx.doi.org/10.1107/S1600536810042728 Text en © Jinfang Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title_full catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title_fullStr catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title_short catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
title_sort catena-poly[[tetra­kis­(hexa­methyl­phospho­ramide-κo)bis­(nitrato-κ(2) o,o′)dysprosium(iii)] [molybdenum(vi)-di-μ-sulfido-silver(i)-di-μ-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009021/
https://www.ncbi.nlm.nih.gov/pubmed/21588894
http://dx.doi.org/10.1107/S1600536810042728
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