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catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
Hexamethylphosphoramide (hmp), tetrathiomolybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009021/ https://www.ncbi.nlm.nih.gov/pubmed/21588894 http://dx.doi.org/10.1107/S1600536810042728 |
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author | Zhang, Jinfang |
author_facet | Zhang, Jinfang |
author_sort | Zhang, Jinfang |
collection | PubMed |
description | Hexamethylphosphoramide (hmp), tetrathiomolybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-antiprismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue. |
format | Text |
id | pubmed-3009021 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30090212010-12-30 catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hexamethylphosphoramide (hmp), tetrathiomolybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n−) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-antiprismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo—Ag—Mo and Ag—Mo—Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue. International Union of Crystallography 2010-10-30 /pmc/articles/PMC3009021/ /pubmed/21588894 http://dx.doi.org/10.1107/S1600536810042728 Text en © Jinfang Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Jinfang catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2) O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title_full |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title_fullStr |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title_full_unstemmed |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title_short |
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ(2)
O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]] |
title_sort | catena-poly[[tetrakis(hexamethylphosphoramide-κo)bis(nitrato-κ(2)
o,o′)dysprosium(iii)] [molybdenum(vi)-di-μ-sulfido-silver(i)-di-μ-sulfido]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3009021/ https://www.ncbi.nlm.nih.gov/pubmed/21588894 http://dx.doi.org/10.1107/S1600536810042728 |
work_keys_str_mv | AT zhangjinfang catenapolytetrakishexamethylphosphoramidekobisnitratok2oodysprosiumiiimolybdenumvidimsulfidosilveridimsulfido |